In　this　work,　a　series　of　BiOBr/MIL-53(Fe)　hybrid　photocatalysts　have　prepared　by　a　facile　co-precipitation　method.　Rhodamine　B　(RhB)　and　carbamazepine　(CBZ)　were　selected　as　the　targets　to　evaluate　the　visible-light　photocatalytic　activity　of　the　prepared　samples.　All　of　the　hybrids　exhibited　better　catalytic　performance　compared　to　the　pristine　BiOBr,　and　the　performance　of　BiOBr/MIL-53　(with　20　wt%　of　MIL-53)　was　the　most　efficient.　The　excellent　performance　can　be　contributed　to　the　incorporation　of　MIL-53(Fe)　which　not　only　form　the　heterojunction　with　BiOBr　to　inhibit　the　recombination　of　the　photoinduced　electron-hole　pairs,　but　also　utilize　the　visible　light　more　effectively.　The　photocatalytic　mechanism　was　studied,　it　shows　that　center　dot　OH　and　h(+)　were　both　the　main　active　species　for　the　degradation　of　contaminants.　Moreover,　the　degradation　pathways　of　CBZ　via　the　photocatalysis　over　BiOBr/MIL-53(Fe)　hybrid　were　presented　based　on　the　determination　of　LC-MS/MS　and　the　results　of　catalytic　mechanisms.　With　the　recent　increase　in　reported　MOFs　materials,　we　believe　a　new　class　of　hybrid　catalytic　materials　is　possible.　This　result　is　conceptually　interesting　as　it　opens　the　door　to　various　MOF-based　BiOBr　materials　for　environmental　purification　and　restoration.