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author:

Xu Gang (Xu Gang.) [1] | Ren Hua (Ren Hua.) [2] | Wu Ming-Hong (Wu Ming-Hong.) [3] (Scholars:吴明红) | Liu Ning (Liu Ning.) [4] | Yuan Qing (Yuan Qing.) [5] | Tang Liang (Tang Liang.) [6] | Wang Liang (Wang Liang.) [7]

Indexed by:

SCIE CSCD

Abstract:

E-beam degradation of bisphenol A (BPA) was carried out, under reductive condition of ethanol-water solution and oxidative condition of acetonitrile-water solution. The degradation efficiency is higher in oxidative condition than that in reductive condition, and increases with the dose but decreased with increasing initial concentration. The BPA radiolysis follows the pseudo-first-order kinetics. Adding H2O2, or neutral condition, does not benefit BPA degradation in oxidative conditions. Pulsed radiolysis was used to investigate mechanism of the BPA radiolysis. The rate constant for BPA reaction with (OH)-O-center dot (1.85 x 10(10) L.mol(-1).s(-1)) is about an order of magnitude higher than that with e(aq)(-) (1.80 x 10(9) L.mol(-1).s(-1)). The degradation products were analyzed by ion chromatograph. Smaller molecules such as formic acid and acetic acid were detected, indicating that (OH)-O-center dot attacks the BPA molecule. The work is of significance for the practical E-beam treatment of waste water containing BPA.

Keyword:

Bisphenol A Degradation E-beam irradiation Pulsed radiolysis

Community:

  • [ 1 ] [Xu Gang]Shanghai Univ, Shanghai Appl Radiat Inst, Shanghai 200444, Peoples R China
  • [ 2 ] [Ren Hua]Shanghai Univ, Shanghai Appl Radiat Inst, Shanghai 200444, Peoples R China
  • [ 3 ] [Wu Ming-Hong]Shanghai Univ, Shanghai Appl Radiat Inst, Shanghai 200444, Peoples R China
  • [ 4 ] [Liu Ning]Shanghai Univ, Shanghai Appl Radiat Inst, Shanghai 200444, Peoples R China
  • [ 5 ] [Yuan Qing]Shanghai Univ, Shanghai Appl Radiat Inst, Shanghai 200444, Peoples R China
  • [ 6 ] [Tang Liang]Shanghai Univ, Shanghai Appl Radiat Inst, Shanghai 200444, Peoples R China
  • [ 7 ] [Wang Liang]Shanghai Univ, Shanghai Appl Radiat Inst, Shanghai 200444, Peoples R China

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Source :

NUCLEAR SCIENCE AND TECHNIQUES

ISSN: 1001-8042

CN: 31-1559/TL

Year: 2011

Issue: 5

Volume: 22

Page: 277-281

0 . 1 9 9

JCR@2011

3 . 6 0 0

JCR@2023

JCR Journal Grade:4

CAS Journal Grade:4

Cited Count:

WoS CC Cited Count: 4

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 5

Affiliated Colleges:

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