Transition-metal and base-free ether synthesis via alcohol-participated yne-allylic substitution - Details

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Abstract：

Ethers　are　among　the　most　important　chemicals　in　organic　synthesis,　the　pharmaceutical　industry,　agrochemical　production,　and　material　science.　C–O　bond　formation　via　substitution　is　one　of　the　most　widely　used　strategies　for　ether　formation.　However,　known　methods　usually　employ　transition-metal　and　bases　to　facilitate　the　process.　In　this　work,　we　describe　the　base-　and　transition-metal-free　ether　formation　via　alcohol　and　phenol-participated　substitution.　The　protocol　allows　access　to　a　large　number　of　ethers　with　enyne　functional　moieties,　and　features　mild　reaction　conditions,　high　efficiency,　and　good　regio-　and　stereoselectivities.　The　reaction　could　be　readily　scaled　up,　and　the　products　could　be　used　in　a　range　of　further　transformations.　©　2023　Fudan　University

Keyword：

Alcohol Base free Ether synthesis Transition-metal free Yne-allylic substitution

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[ 1 ] [Xu C.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
[ 2 ] [Xu C.]State Key Laboratory of Structural Chemistry, And Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Center for Excellence in Molecular Synthesis, Fujian Institute of Research on the Structure of Matter, University of Chinese Academy of Sciences, Fuzhou, 350100, China
[ 3 ] [Luo Y.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
[ 4 ] [Luo Y.]State Key Laboratory of Structural Chemistry, And Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Center for Excellence in Molecular Synthesis, Fujian Institute of Research on the Structure of Matter, University of Chinese Academy of Sciences, Fuzhou, 350100, China
[ 5 ] [Niu S.]State Key Laboratory of Structural Chemistry, And Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Center for Excellence in Molecular Synthesis, Fujian Institute of Research on the Structure of Matter, University of Chinese Academy of Sciences, Fuzhou, 350100, China
[ 6 ] [Gong F.]State Key Laboratory of Structural Chemistry, And Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Center for Excellence in Molecular Synthesis, Fujian Institute of Research on the Structure of Matter, University of Chinese Academy of Sciences, Fuzhou, 350100, China
[ 7 ] [Lan S.]State Key Laboratory of Structural Chemistry, And Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Center for Excellence in Molecular Synthesis, Fujian Institute of Research on the Structure of Matter, University of Chinese Academy of Sciences, Fuzhou, 350100, China
[ 8 ] [Luo B.]Pingxiang University, Pingxiang, 337055, China
[ 9 ] [Liu J.]Orthopedics Department, Guangdong Provincial Hospital of Traditional Chinese Medicine, The Second Affiliated Hospital of Guangzhou University of Chinese Medicine, Guangzhou, 510120, China
[ 10 ] [Yang S.]State Key Laboratory of Structural Chemistry, And Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Center for Excellence in Molecular Synthesis, Fujian Institute of Research on the Structure of Matter, University of Chinese Academy of Sciences, Fuzhou, 350100, China
[ 11 ] [Fang X.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
[ 12 ] [Fang X.]State Key Laboratory of Structural Chemistry, And Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, Center for Excellence in Molecular Synthesis, Fujian Institute of Research on the Structure of Matter, University of Chinese Academy of Sciences, Fuzhou, 350100, China

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Transition-metal and base-free ether synthesis via alcohol-participated yne-allylic substitution
2024，GREEN SYNTHESIS AND CATALYSIS

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Source ：

Green Synthesis and Catalysis

ISSN： 2666-5549

Year： 2024

Issue： 4

Volume： 5

Page： 303-309

8 . 3 0 0

JCR@2023

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SCOPUS Cited Count： 6

ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 0

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