Layer by Layer Spraying Fabrication of Aggregation-Induced Emission Metal-Organic Frameworks Thin Film - Details

author：

Yang, X.-X. (Yang, X.-X..) ^[1] | Li, C. (Li, C..) ^[2] | Chen, S.-M. (Chen, S.-M..) ^[3] | Gu, Z.-G. (Gu, Z.-G..) ^[4] | Zhang, J. (Zhang, J..) ^[5]

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Abstract：

The　development　of　new　metal-organic　frameworks　(MOFs)　thin　films　is　important　for　expanding　their　functions　and　applications.　Herein,　we　first　report　a　new　kind　of　MOF　thin　film　by　using　aggregation-induced　emission　(AIE)　dicarboxyl　ligand　through　a　liquid-phase　epitaxial　(LPE)　layer-by-layer　(LBL)　spraying　method　(named　AIE　surface-coordinated　metal-organic　frameworks　thin　film,　AIE-SURMOF).　The　obtained　AIE-SURMOF　Zn4O(TPE)3　(ZnTPE)　has　highly　growth　orientation　and　homogeneous　thin　film,　showing　strong　fluorescent　property.　Furthermore,　by　loading　chiral　guest　in　the　MOF　pore,　the　formed　chiral　encapsulated　AIE-SURMOF　can　clearly　indicate　obvious　circularly　polarized　luminescence　performance　with　glum　of　0.01.　This　study　provides　new　MOF　thin　film　and　new　strategy　for　expanding　function　and　application　of　MOF　materials.　©　2024　Wiley-VCH　GmbH.

Keyword：

aggregation-induced emission circularly polarized luminescence metal-organic framework thin film

Community：

[ 1 ] [Yang X.-X.]College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 2 ] [Yang X.-X.]Fujian College, University of Chinese Academy of Sciences, Fuzhou, 350002, China
[ 3 ] [Yang X.-X.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
[ 4 ] [Li C.]College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 5 ] [Li C.]Fujian College, University of Chinese Academy of Sciences, Fuzhou, 350002, China
[ 6 ] [Li C.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
[ 7 ] [Chen S.-M.]College of Chemistry, Fuzhou University, Fuzhou, 350108, China
[ 8 ] [Gu Z.-G.]Fujian College, University of Chinese Academy of Sciences, Fuzhou, 350002, China
[ 9 ] [Gu Z.-G.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
[ 10 ] [Gu Z.-G.]University of Chinese Academy of Sciences, Beijing, 100049, China
[ 11 ] [Zhang J.]Fujian College, University of Chinese Academy of Sciences, Fuzhou, 350002, China
[ 12 ] [Zhang J.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
[ 13 ] [Zhang J.]University of Chinese Academy of Sciences, Beijing, 100049, China

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Source ：

Chemistry - A European Journal

ISSN： 0947-6539

Year： 2024

Issue： 24

Volume： 30

3 . 9 0 0

JCR@2023

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ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 1

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