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The development of new metal-organic frameworks (MOFs) thin films is important for expanding their functions and applications. Herein, we first report a new kind of MOF thin film by using aggregation-induced emission (AIE) dicarboxyl ligand through a liquid-phase epitaxial (LPE) layer-by-layer (LBL) spraying method (named AIE surface-coordinated metal-organic frameworks thin film, AIE-SURMOF). The obtained AIE-SURMOF Zn4O(TPE)3 (ZnTPE) has highly growth orientation and homogeneous thin film, showing strong fluorescent property. Furthermore, by loading chiral guest in the MOF pore, the formed chiral encapsulated AIE-SURMOF can clearly indicate obvious circularly polarized luminescence performance with glum of 0.01. This study provides new MOF thin film and new strategy for expanding function and application of MOF materials. A new kind of metal-organic framework (MOF) thin film were prepared by using aggregation-induced emission (AIE) based ligand through a liquid-phase epitaxial (LPE) layer-by-layer (LBL) spraying method, which is named AIE surface-coordinated metal-organic frameworks thin film (AIE-SURMOF). The obtained AIE-SURMOF has highly growth orientation and homogeneous thin film, showing strong fluorescent property. Furthermore, by loading chiral guest in the MOF pore, the formed chiral encapsulated AIE-SURMOF can clearly indicate obvious circularly polarized luminescence performance. image
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CHEMISTRY-A EUROPEAN JOURNAL
ISSN: 0947-6539
Year: 2024
Issue: 24
Volume: 30
3 . 9 0 0
JCR@2023
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 2
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