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author:

Yang, Longwen (Yang, Longwen.) [1] | Du, Aochen (Du, Aochen.) [2] | Zheng, Xingke (Zheng, Xingke.) [3] | Ye, Yun (Ye, Yun.) [4] | Chen, Enguo (Chen, Enguo.) [5] | Xu, Sheng (Xu, Sheng.) [6] | Guo, Tailiang (Guo, Tailiang.) [7]

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EI

Abstract:

All-inorganic perovskite quantum dots (PQDs) have excellent photoelectric performance, such as high photoluminescence quantum yield (PLQY), narrow full width at half-maximum (FWHM), and emission spectra covering the visible light wavelength. The emission color can be tuned over the full visible spectral region making them promising for white-light-emitting diodes (WLEDs). Further control over the optical and magnetic properties of PQDs can be achieved through doping of transition metal ions such asMn2C ions. In this paper, a rapid doping method is employed at room temperature by using strong-acid cation-exchange resin during the metal ions doping process, which shortens the doping time, and MnVCsPb.Cl=Br/3 QDs were obtained. By controlling the reaction time between strong-acid cation-exchange resin and PQDs,we achieve different levels of manganese doping, resulting in a new, to the best of our knowledge, fluorescence peak at 600 nm. The introduction of strong-acid cation-exchange resin preserves the integrity of thePQDstructure, while completing the doping within 30 min.Due to the low cost and mild reaction conditions of resin, it is expected that theMnVCsPb.Cl=Br/3 QDs can be mass-produced in large quantities. In addition, in order to provide high-quality white light emission, and prevent anion exchange reactions when mixed with CsPbBr3 QDs, the CsPbBr3 QDs are coated with silicon. Finally, by combining ultraviolet-lightemitting diodes (UVLEDs) with the aforementioned PQD mixture, this paper successfully fabricates WLEDs and demonstrates its excellent photoelectric performance. The constructed WLEDs produce warm white light with a high color rendering index (CRI) of 91 and a high correlated color temperature (CCT) of 5966 K, and the luminous efficacy (LE) ofWLEDsis 41 lmW-1. © 2024 Optica Publishing Group.

Keyword:

Bromine compounds Cesium compounds Color Emission spectroscopy Lead compounds Metal ions Nanocrystals Perovskite Positive ions Semiconductor quantum dots Transition metals

Community:

  • [ 1 ] [Yang, Longwen]College of Physics and Information Engineering, Fuzhou University, Fuzhou; 350108, China
  • [ 2 ] [Yang, Longwen]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou; 350108, China
  • [ 3 ] [Du, Aochen]College of Physics and Information Engineering, Fuzhou University, Fuzhou; 350108, China
  • [ 4 ] [Du, Aochen]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou; 350108, China
  • [ 5 ] [Zheng, Xingke]College of Physics and Information Engineering, Fuzhou University, Fuzhou; 350108, China
  • [ 6 ] [Zheng, Xingke]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou; 350108, China
  • [ 7 ] [Ye, Yun]College of Physics and Information Engineering, Fuzhou University, Fuzhou; 350108, China
  • [ 8 ] [Ye, Yun]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou; 350108, China
  • [ 9 ] [Chen, Enguo]College of Physics and Information Engineering, Fuzhou University, Fuzhou; 350108, China
  • [ 10 ] [Chen, Enguo]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou; 350108, China
  • [ 11 ] [Xu, Sheng]College of Physics and Information Engineering, Fuzhou University, Fuzhou; 350108, China
  • [ 12 ] [Xu, Sheng]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou; 350108, China
  • [ 13 ] [Guo, Tailiang]College of Physics and Information Engineering, Fuzhou University, Fuzhou; 350108, China
  • [ 14 ] [Guo, Tailiang]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou; 350108, China

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Source :

Journal of the Optical Society of America B: Optical Physics

ISSN: 0740-3224

Year: 2024

Issue: 3

Volume: 41

Page: 809-819

1 . 8 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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