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author:

Cao, Hong (Cao, Hong.) [1] | Zhang, Bing (Zhang, Bing.) [2] | Wang, Wei (Wang, Wei.) [3] | Li, Yongzhao (Li, Yongzhao.) [4] | Jia, Mengke (Jia, Mengke.) [5] | Yu, Weihe (Yu, Weihe.) [6] | Liu, Longmin (Liu, Longmin.) [7] | Huang, Jianying (Huang, Jianying.) [8] (Scholars:黄剑莹) | Chen, Huaiyin (Chen, Huaiyin.) [9] (Scholars:陈怀银) | Lai, Yuekun (Lai, Yuekun.) [10] (Scholars:赖跃坤) | Cai, Weilong (Cai, Weilong.) [11] (Scholars:蔡伟龙)

Indexed by:

EI Scopus SCIE

Abstract:

Polyphenylene sulfide (PPS), commonly used as a core material for high -temperature flue gas treatment, exhibits elevated viscosity when processed even at temperature exceeding 280 degrees C. In this study, a novel high-flowability PPS -based composite was fabricated through the incorporation of graphitic carbon nitride (g-C3N4) via a wellestablished melt extrusion procedure. The enhancement of flowability in PPS was verified, and the material's texture structures and fundamental properties of composites with varying contents were determined. The composites exhibit well -dispersed g-C3N4, a significant reduction in shear viscosity (>10 %), a notable increase in melt index (>30 %), improved crystallinity, and comparable or superior performance compared to pure PPS. When the g-C(3)N(4 )was introduced into the PPS matrix, a phase -separated composite structure was formed. This structure reduces the entanglement degree between the PPS molecular chains and provides more space for freemovement of the PPS chains, and thus the improvement in flowability for the composites can be clearly demonstrated. Therefore, g-C(3)N(4 )can be used as a novel flow modifier to enhance the flowability and stability of PPS resin without compromising its fundamental properties, which offers significant prospects for improving productivity, optimizing energy usage, and managing costs for PPS -based products.

Keyword:

Graphitic carbon nitride (g-C3N4) High flowability Melt blending Phase-separated structure Polyphenylene sulfide (PPS)

Community:

  • [ 1 ] [Zhang, Bing]Qingyuan Innovat Lab, Quanzhou 362801, Peoples R China
  • [ 2 ] [Li, Yongzhao]Qingyuan Innovat Lab, Quanzhou 362801, Peoples R China
  • [ 3 ] [Jia, Mengke]Qingyuan Innovat Lab, Quanzhou 362801, Peoples R China
  • [ 4 ] [Yu, Weihe]Qingyuan Innovat Lab, Quanzhou 362801, Peoples R China
  • [ 5 ] [Liu, Longmin]Qingyuan Innovat Lab, Quanzhou 362801, Peoples R China
  • [ 6 ] [Chen, Huaiyin]Qingyuan Innovat Lab, Quanzhou 362801, Peoples R China
  • [ 7 ] [Lai, Yuekun]Qingyuan Innovat Lab, Quanzhou 362801, Peoples R China
  • [ 8 ] [Cai, Weilong]Qingyuan Innovat Lab, Quanzhou 362801, Peoples R China
  • [ 9 ] [Cao, Hong]Fuzhou Univ, Coll Chem Engn, Fuzhou 350116, Peoples R China
  • [ 10 ] [Zhang, Bing]Fuzhou Univ, Coll Chem Engn, Fuzhou 350116, Peoples R China
  • [ 11 ] [Wang, Wei]Fuzhou Univ, Coll Chem Engn, Fuzhou 350116, Peoples R China
  • [ 12 ] [Huang, Jianying]Fuzhou Univ, Coll Chem Engn, Fuzhou 350116, Peoples R China
  • [ 13 ] [Chen, Huaiyin]Fuzhou Univ, Coll Chem Engn, Fuzhou 350116, Peoples R China
  • [ 14 ] [Lai, Yuekun]Fuzhou Univ, Coll Chem Engn, Fuzhou 350116, Peoples R China
  • [ 15 ] [Cai, Weilong]Fuzhou Univ, Coll Chem Engn, Fuzhou 350116, Peoples R China

Reprint 's Address:

  • 陈怀银 赖跃坤 蔡伟龙

    [Chen, Huaiyin]Fuzhou Univ, Coll Chem Engn, Fuzhou 350116, Peoples R China;;[Lai, Yuekun]Fuzhou Univ, Coll Chem Engn, Fuzhou 350116, Peoples R China;;[Cai, Weilong]Fuzhou Univ, Coll Chem Engn, Fuzhou 350116, Peoples R China

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Source :

POLYMER

ISSN: 0032-3861

Year: 2024

Volume: 293

4 . 1 0 0

JCR@2023

Cited Count:

WoS CC Cited Count: 2

SCOPUS Cited Count: 2

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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