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Sintering for large-sized, stoichiometric Bi0.5Na0.5TiO3 (BNT) ceramics is of great challenge due to the loss of volatile Bi/Na at A-site of perovskite structure. In this work, BNT ceramic tile with the size of similar to 10 x 10 cm2 and near-stoichiometric composition has been successfully fabricated by Isobam-assisted gelcasting process, followed by sintering with 1150 degrees C calcined power bed. The powder bed used and sintering duration were found to have a great influence on the formation of the Na-deficient phase (Bi4.5Na0.5Ti4O15) in the ceramics, and the strategies to eliminate it have been explored. The obtained ceramics exhibit a dielectric constant/loss of 673.6/0.039 at 1 kHz, as well as an electrostrictive strain of similar to 0.07% which corresponds to a converse piezoelectric constant d33*$d_{33}<^>*$ of 105.2 pm/V. Our work thus provides an effective approach to prepare large-sized and stoichiometric BNT ceramics.
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JOURNAL OF THE AMERICAN CERAMIC SOCIETY
ISSN: 0002-7820
Year: 2024
Issue: 6
Volume: 107
Page: 4086-4095
3 . 5 0 0
JCR@2023
CAS Journal Grade:2
Cited Count:
WoS CC Cited Count: 1
SCOPUS Cited Count: 1
ESI Highly Cited Papers on the List: 0 Unfold All
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Chinese Cited Count:
30 Days PV: 0
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