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author:

Guo, Huilu (Guo, Huilu.) [1] | Zhu, Minmin (Zhu, Minmin.) [2] (Scholars:朱敏敏) | Zhao, Yida (Zhao, Yida.) [3] | Du, Zehui (Du, Zehui.) [4]

Indexed by:

EI Scopus SCIE

Abstract:

Sintering for large-sized, stoichiometric Bi0.5Na0.5TiO3 (BNT) ceramics is of great challenge due to the loss of volatile Bi/Na at A-site of perovskite structure. In this work, BNT ceramic tile with the size of similar to 10 x 10 cm2 and near-stoichiometric composition has been successfully fabricated by Isobam-assisted gelcasting process, followed by sintering with 1150 degrees C calcined power bed. The powder bed used and sintering duration were found to have a great influence on the formation of the Na-deficient phase (Bi4.5Na0.5Ti4O15) in the ceramics, and the strategies to eliminate it have been explored. The obtained ceramics exhibit a dielectric constant/loss of 673.6/0.039 at 1 kHz, as well as an electrostrictive strain of similar to 0.07% which corresponds to a converse piezoelectric constant d33*$d_{33}<^>*$ of 105.2 pm/V. Our work thus provides an effective approach to prepare large-sized and stoichiometric BNT ceramics.

Keyword:

BNT dielectric electrostriction sintering stoichiometry

Community:

  • [ 1 ] [Guo, Huilu]Nanyang Technol Univ, Sch Mat Sci & Engn, 50 Nanyang Ave, Singapore 639798, Singapore
  • [ 2 ] [Zhao, Yida]Nanyang Technol Univ, Sch Mat Sci & Engn, 50 Nanyang Ave, Singapore 639798, Singapore
  • [ 3 ] [Du, Zehui]Nanyang Technol Univ, Sch Mat Sci & Engn, 50 Nanyang Ave, Singapore 639798, Singapore
  • [ 4 ] [Zhu, Minmin]Fuzhou Univ, Coll Phys & Informat Engn, Fuzhou 350116, Peoples R China
  • [ 5 ] [Zhu, Minmin]Fuzhou Univ, FZU Jinjiang Joint Inst Microelect, Jinjiang Sci & Educ Pk, Jinjiang, Peoples R China

Reprint 's Address:

  • 朱敏敏

    [Du, Zehui]Nanyang Technol Univ, Sch Mat Sci & Engn, 50 Nanyang Ave, Singapore 639798, Singapore;;[Zhu, Minmin]Fuzhou Univ, Coll Phys & Informat Engn, Fuzhou 350116, Peoples R China

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Source :

JOURNAL OF THE AMERICAN CERAMIC SOCIETY

ISSN: 0002-7820

Year: 2024

Issue: 6

Volume: 107

Page: 4086-4095

3 . 5 0 0

JCR@2023

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count: 1

SCOPUS Cited Count: 1

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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