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Dielectric materials with colossal permittivity (CP, epsilon(r) > 10(4)) have attracted the increasing interest of researchers due to their enormous potential in the fields of sensor, capacitor, energy storage, etc. However, for the explored CP materials, their grains are too large to apply. To control grain growth, the sintering aids of MgO-Al2O3-SiO2 (MAS) cordierite glass and common suppression grain growth of MgO have been introduced to BaTiO3-0.004Y(2)O(3)-0.006MnO(2) ceramics derived from the commercial BaTiO3 powder with the average grain size of 300 nm. After controlling grain growth, the fine grains with the average grain size of d(g) similar to 300 nm and CP are achieved in BaTiO3 based ceramics sintered in reducing atmosphere. Notably, excellent temperature stability with Delta epsilon(r)/epsilon(r25 degrees C) lower than 17 % is gained for the present BaTiO3 based ceramics in the temperature range of -60 to 155 degrees C, meeting the X8S specification (Delta C/C-25 degrees C <=+/- 22 %, -55 degrees C-150 degrees C). Based on the X-ray photoelectron spectroscopy (XPS) and Raman spectra, the outstanding dielectric properties of the present BaTiO3 based ceramics is ascribed to the electron-pinned defect-dipole (EPDD) effect induced by Y-Ti '-Y-Ba(center dot ), Ti-Ti '-V-o(center dot center dot)-Ti-Ti ' and Y-Ti '-V-o(center dot center dot)-Ti-Ti ' defect dipoles. The present BaTiO3 based fine ceramics with colossal permittivity (similar to 2.9 x 10(4)), low loss (similar to 0.03) at 1 kHz and room temperature, excellent temperature stability and high resistivity of 3.54 x 10(9) Omega cm is a promising candidate for the multilayer ceramics capacitor (MLCC).
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CERAMICS INTERNATIONAL
ISSN: 0272-8842
Year: 2024
Issue: 7
Volume: 50
Page: 11980-11988
5 . 1 0 0
JCR@2023
Cited Count:
WoS CC Cited Count: 6
SCOPUS Cited Count: 8
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
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