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author:

Wei, Xiaowei (Wei, Xiaowei.) [1] | Lv, Xiang (Lv, Xiang.) [2] | Cui, Anyang (Cui, Anyang.) [3] | Zhao, Chunlin (Zhao, Chunlin.) [4] (Scholars:赵纯林) | Ma, Yinchang (Ma, Yinchang.) [5] | Zhang, Xi-Xiang (Zhang, Xi-Xiang.) [6] | Yuan, Youyou (Yuan, Youyou.) [7] | Wu, Jiagang (Wu, Jiagang.) [8]

Indexed by:

EI Scopus SCIE

Abstract:

For environmentally benign lead-free ferroelectric ceramics, the trait of temperature-dependent phase boundary renders ceramics with intrinsic temperature sensitivity, obstructing them toward practical applications. Recently, laminated composite ceramics were widely implemented to solve temperature instability. However, such 2-2 type structure exhibits inherent limitations on properties promotion. Given this, the present work proposes a novel strategy of 3-3-like heterostructure engineering to tackle the problem. Compared to the laminated counterpart, 3-3-like ceramic shows boosted dielectric, ferroelectric and strain properties. Significantly, its electrocaloric (EC) operating range is expanded from 18 to 49 degrees C, two-fold wider than the laminated one, while a large EC temperature change of 0.66 K@30 kV/cm is maintained, which shows great property advantages to that of state-of-art lead-free ceramics. The superior performance benefits from the relatively uniform field dispersion of 3-3-like heterogeneity. As a contrast, sharp interface divergence causes abnormal field distribution and phase destabilization in laminated structure, which undermines the electrical properties and limits temperature stability. This work offers a favorable strategy for designing high-performance lead-free materials with desirable temperature reliability.

Keyword:

3-3-like Barium titanate Heterostructure engineering Lead-free Temperature stability

Community:

  • [ 1 ] [Wei, Xiaowei]Sichuan Univ, Coll Mat Sci & Engn, Chengdu 610065, Peoples R China
  • [ 2 ] [Lv, Xiang]Sichuan Univ, Coll Mat Sci & Engn, Chengdu 610065, Peoples R China
  • [ 3 ] [Wu, Jiagang]Sichuan Univ, Coll Mat Sci & Engn, Chengdu 610065, Peoples R China
  • [ 4 ] [Cui, Anyang]Shanghai Normal Univ, Dept Phys, Key Lab Optoelect Mat & Device, Shanghai 200234, Peoples R China
  • [ 5 ] [Zhao, Chunlin]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 6 ] [Ma, Yinchang]King Abdullah Univ Sci & Technol, Div Phys Sci & Engn, Thuwal 239556900, Saudi Arabia
  • [ 7 ] [Zhang, Xi-Xiang]King Abdullah Univ Sci & Technol, Div Phys Sci & Engn, Thuwal 239556900, Saudi Arabia
  • [ 8 ] [Yuan, Youyou]King Abdullah Univ Sci & Technol, Core Labs, Thuwal 239556900, Saudi Arabia
  • [ 9 ] [Wu, Jiagang]Sichuan Univ, Coll Phys, Chengdu 610064, Peoples R China

Reprint 's Address:

  • [Lv, Xiang]Sichuan Univ, Coll Mat Sci & Engn, Chengdu 610065, Peoples R China;;[Wu, Jiagang]Sichuan Univ, Coll Mat Sci & Engn, Chengdu 610065, Peoples R China;;[Cui, Anyang]Shanghai Normal Univ, Dept Phys, Key Lab Optoelect Mat & Device, Shanghai 200234, Peoples R China;;

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Source :

ACTA MATERIALIA

ISSN: 1359-6454

Year: 2025

Volume: 285

8 . 3 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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