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author:

Yu, Li (Yu, Li.) [1] | Huang, Chunzhi (Huang, Chunzhi.) [2] | Gong, Yue (Gong, Yue.) [3] | Zheng, Shixiang (Zheng, Shixiang.) [4] | Zhou, Piaopiao (Zhou, Piaopiao.) [5] | Zhang, Xuan (Zhang, Xuan.) [6] | Zou, Zhigang (Zou, Zhigang.) [7] | Lyu, Xiaolin (Lyu, Xiaolin.) [8] (Scholars:吕晓林)

Indexed by:

EI Scopus SCIE

Abstract:

Polymer ionic conductors have shown great promise as iontronic sensors for flexible wearable devices and intelligent machines. A series of exquisitely designed hydrogels, ionogels, and ionic elastomers have good mechanical properties, such as super stretchability and high elasticity. However, most gels tend to exhibit softening or linear mechanoresponsive behavior when subjected to stress, which is completely different from the strain-stiffening behavior of the biological tissues. Therefore, designing polymer ionic conductors with good mechanical properties and strain-stiffening ability remains a challenge, which is critical in improving the reliability and durability of iontronic sensing. Here, we propose a strong/weak ionic interaction strategy to develop poly(ionic liquid) elastomers (PILEs) through the copolymerization of imidazolium ionic liquid monomers and acrylate monomers. The design allows weak ionic interactions to impart softness to the polymer network, while strong ionic interactions stiffen the network during stretching. The resulting transparent PILE possesses ultrastretchability, immense strain stiffening, good elasticity, high toughness, and puncture resistance. The PILE also shows antibacterial ability and good adhesion due to high-content charge groups in the polymer network. These combined properties make the PILE an excellent candidate for iontronic sensors, with excellent stability and sensitivity to temperature and strain, demonstrating great potential in wearable devices and human-machine interfaces.

Keyword:

Community:

  • [ 1 ] [Yu, Li]Fuzhou Univ, Coll Mat Sci & Engn, Key Lab Adv Mat Technol, Int HongKong Macao & Taiwan Joint Lab Adv Mat Tech, Fuzhou 350108, Fujian, Peoples R China
  • [ 2 ] [Huang, Chunzhi]Fuzhou Univ, Coll Mat Sci & Engn, Key Lab Adv Mat Technol, Int HongKong Macao & Taiwan Joint Lab Adv Mat Tech, Fuzhou 350108, Fujian, Peoples R China
  • [ 3 ] [Gong, Yue]Fuzhou Univ, Coll Mat Sci & Engn, Key Lab Adv Mat Technol, Int HongKong Macao & Taiwan Joint Lab Adv Mat Tech, Fuzhou 350108, Fujian, Peoples R China
  • [ 4 ] [Zou, Zhigang]Fuzhou Univ, Coll Mat Sci & Engn, Key Lab Adv Mat Technol, Int HongKong Macao & Taiwan Joint Lab Adv Mat Tech, Fuzhou 350108, Fujian, Peoples R China
  • [ 5 ] [Lyu, Xiaolin]Fuzhou Univ, Coll Mat Sci & Engn, Key Lab Adv Mat Technol, Int HongKong Macao & Taiwan Joint Lab Adv Mat Tech, Fuzhou 350108, Fujian, Peoples R China
  • [ 6 ] [Zheng, Shixiang]Fujian Med Univ, Union Hosp, Dept Crit Care Med, Fuzhou 350108, Fujian, Peoples R China
  • [ 7 ] [Zhou, Piaopiao]Fujian Med Univ, Union Hosp, Dept Crit Care Med, Fuzhou 350108, Fujian, Peoples R China
  • [ 8 ] [Zou, Zhigang]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Fujian, Peoples R China
  • [ 9 ] [Lyu, Xiaolin]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Fujian, Peoples R China
  • [ 10 ] [Zhang, Xuan]Ningbo Univ, Inst Drug Discovery Technol, Ningbo 315211, Peoples R China
  • [ 11 ] [Zhang, Xuan]Ningbo Univ, Qian Xuesen Collaborat Res Ctr Astrochem & Space L, Ningbo 315211, Peoples R China
  • [ 12 ] [Zou, Zhigang]Nanjing Univ, Coll Engn & Appl Sci, Ecomat & Renewable Energy Res Ctr, Nanjing 210093, Peoples R China

Reprint 's Address:

  • 吕晓林

    [Lyu, Xiaolin]Fuzhou Univ, Coll Mat Sci & Engn, Key Lab Adv Mat Technol, Int HongKong Macao & Taiwan Joint Lab Adv Mat Tech, Fuzhou 350108, Fujian, Peoples R China;;[Zhou, Piaopiao]Fujian Med Univ, Union Hosp, Dept Crit Care Med, Fuzhou 350108, Fujian, Peoples R China;;[Lyu, Xiaolin]Fujian Sci & Technol Innovat Lab Optoelect Informa, Fuzhou 350108, Fujian, Peoples R China;;[Zhang, Xuan]Ningbo Univ, Inst Drug Discovery Technol, Ningbo 315211, Peoples R China;;[Zhang, Xuan]Ningbo Univ, Qian Xuesen Collaborat Res Ctr Astrochem & Space L, Ningbo 315211, Peoples R China

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Source :

MACROMOLECULES

ISSN: 0024-9297

Year: 2024

Issue: 5

Volume: 57

Page: 2339-2350

5 . 1 0 0

JCR@2023

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 1

SCOPUS Cited Count: 2

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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