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author:

Li, Z. (Li, Z..) [1] | Liu, Y. (Liu, Y..) [2] | Wei, Y. (Wei, Y..) [3] | Yan, S. (Yan, S..) [4] | Wu, M. (Wu, M..) [5]

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Scopus

Abstract:

Rechargeable aqueous zinc-ion batteries (ZIBs) are recognized as a potential candidate for large-scale energy storage due to its high-security and low-expense aspects. However, the poor structural stability and sluggish redox kinetics of cathode material lead to the serious capacity fading and bad rate performances, which hinders its practical applications. Herein, a novel one-step pyrolysis strategy is conducted for fabricating the composites of multicomponent active substances (including WO3, Bi and Bi2O3) embedded in amorphous N-doped carbon matrix (BWO@C) using polydopamine-coated Bi2WO6 micro-flowers as the precursors. The amorphous nitrogen-doped carbon endows BWO@C composite to possess more active-sites and higher electrical conductivity for rapid electrons/ions transport, and meanwhile the active substances could be effectively utilized even undergoing thousands of charge/discharge cycles. Therefore, the resulting BWO@C as cathode for aqueous ZIBs exhibits satisfying rate performances as well as outstanding cycling stability. This work provides a simple and efficient pathway for designing the cathode materials with high conductivity and high structural stability to achieve remarkable performances and long life-span of aqueous ZIBs. © 2024 Elsevier B.V.

Keyword:

Aqueous zinc-ion batteries Carbon matrix Cathode materials Multicomponent composites Structural stability

Community:

  • [ 1 ] [Li Z.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 2 ] [Liu Y.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 3 ] [Wei Y.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 4 ] [Wei Y.]College of Chemistry, Fuzhou University, Fuzhou, 350108, China
  • [ 5 ] [Yan S.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 6 ] [Yan S.]College of Chemistry, Fuzhou University, Fuzhou, 350108, China
  • [ 7 ] [Wu M.]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, China
  • [ 8 ] [Wu M.]University of Chinese Academy of Sciences, Beijing, 100049, China

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Source :

Journal of Power Sources

ISSN: 0378-7753

Year: 2024

Volume: 602

8 . 1 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 1

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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