In　this　study,　the　adsorption　behavior　of　gallium　ions　on　a　synthesized　hydroxamic　acid　resin　from　sulfuric　acid　solution　was　investigated,　aiming　to　recover　Ga　directly　from　pressure　leaching　solution　in　zinc　hydrometallurgical　plant.　Hydroxamic　acid　chelating　resin　(HA-PDR)　was　prepared　by　introducing　hydroxamic　acid　groups　into　the　pre-made　polyacrylate　resin　(PDR)　with　methyl　ester　group　through　hydroxylamine　reaction.　Polyacrylate-divinylbenzene　hydroxamic　resins　with　a　nitrogen　content　of　up　to　3.85　%　were　obtained　at　a　divinylbenzene　(DVB)　content　of　13　%　and　an　optimal　raw　material　ratio　of　NH2OH　&　sdot;HCl:　NaOH:　-CH3　=　4:4.5:1　(molar　ratio).　The　obtained　materials　was　characterized　using　FTIR,　XPS　and　SEM　to　verify　the　successful　introduction　of　hydroxamic　acid　groups.　The　results　of　adsorption　experiments　showed　that　the　adsorption　capacity　of　27.65　mg/g　could　be　obtained　with　a　chemical,　multilayered,　and　heterogeneous　adsorption　process,　and　film　diffusion　and　intra-particle　diffusion　rate　controlled　mainly　the　adsorption　efficiency.　It　has　been　proven　that　polyacrylate-divinylbenzene　hydroxamic　resins　has　extremely　high　adsorption　selectivity　for　gallium　in　sulfuric　acid　solution,　and　the　desorption　effect　is　obvious,　which　can　be　applied　promisingly　in　the　industrial　development　of　gallium　extraction　technology　from　zinc　leaching　residue　in　sulfuric　acid　system.