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Abstract:
The Fenton reaction, an effective advanced oxidation process (AOP) for degrading organic pollutants, requires the addition of H 2 O 2 that is expensive and not environmentally friendly to some extent. It has been reported that piezocatalysis can generate H 2 O 2 under mechanical excitation. Therefore, it is promising to carry out the Fenton catalysis utilizing in situ H 2 O 2 generated by piezocatalysis. However, the current piezocatalysis-assisted Fenton (Piezo-Fenton) reaction was realized by adding piezoelectric nanoparticles and Fe(II) ions to pollutant solutions, which would induce more iron-based chemicals that are not easy to recycle. Herein, Fe 3 O 4 -BaTiO 3 nanocomposites were prepared to demonstrate the feasibility of piezo-Fenton catalysis without the addition of H 2 O 2 or Fe(II) ions. The organic dye degradation efficiency of 98.2% is obtained using Fe 3 O 4 -BaTiO 3 nanocomposites in the acidic solution, one-third and two-thrid greater than that of pure piezocatalysis and that of iron-based Fenton reaction, respectively. Moreover, since the piezocatalysis process is the rate-determining step of the whole piezo-Fenton reaction, all the H 2 O 2 generated can be consumed. Considering that the solid nanocomposites can be magnetically recycled, piezo-Fenton catalysis leaves no additional chemicals in clean water and thus provides an environmentally friendly and low-cost approach for organic dye degradation.
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CHEMICAL ENGINEERING JOURNAL
ISSN: 1385-8947
Year: 2024
Volume: 487
1 3 . 4 0 0
JCR@2023
Cited Count:
WoS CC Cited Count: 12
SCOPUS Cited Count: 14
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
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