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author:

Wang, R. (Wang, R..) [1] | Li, Y. (Li, Y..) [2] | Zhu, J. (Zhu, J..) [3] | Zheng, Q. (Zheng, Q..) [4] | Deng, H. (Deng, H..) [5] | Zhang, C. (Zhang, C..) [6] | Wang, W. (Wang, W..) [7] | Meng, Q. (Meng, Q..) [8] | Wu, J. (Wu, J..) [9] | Li, D. (Li, D..) [10] | Cheng, S. (Cheng, S..) [11]

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Scopus

Abstract:

Constructing 2D/3D perovskite heterostructures with organic molecules is key to improving the power conversion efficiency (PCE) and stability of perovskite solar cells (PSCs). However, a comprehensive understanding of the inhibitory relationship between the 2D perovskite layer and ion migration at the interface is still lacking. In this study, we use different alkyl ammonium iodides to build 2D/3D perovskite heterostructures. The research results show that both the chain length of alkyl and amino group count in alkyl ammonium iodide can significantly affect the crystal structure orientation of the 2D perovskite layer. A Dion-Jacobson (DJ) 2D/3D structure treated with ODADI shows superior defect passivation and carrier extraction, leading to PSCs with a 24.51 % PCE. Furthermore, the perovskite based on ODA cations eliminates the influence of Van der Waals interaction in perovskite based on BA or OA cations, which improves the stability of the lattice structure, and significantly inhibits ion migration. Therefore, after a maximum power point stability test of 1500 h, devices retain approximately 88 % of their initial PCE. This work offers fresh insights into optimizing interfaces in 2D/3D PSCs by selecting suitable organic molecules. © 2024

Keyword:

2D/3d perovskite heterostructure Defect passivation Ion migration Perovskite solar cells Stability

Community:

  • [ 1 ] [Wang R.]College of Physics and Information Engineering, Institute of Micro-Nano Devices and Solar Cells, Fuzhou University, Fuzhou, 350108, China
  • [ 2 ] [Wang R.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou, 350108, China
  • [ 3 ] [Li Y.]Key Laboratory for Renewable Energy, Chinese Academy of Sciences, Beijing Key, Laboratory for New Energy Materials and Devices, Institute of Physics, Beijing, 100190, China
  • [ 4 ] [Zhu J.]Fujian Key Laboratory of Electrochemical Energy Storage Materials, Fuzhou University, Fuzhou, 350116, China
  • [ 5 ] [Zheng Q.]College of Physics and Information Engineering, Institute of Micro-Nano Devices and Solar Cells, Fuzhou University, Fuzhou, 350108, China
  • [ 6 ] [Zheng Q.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou, 350108, China
  • [ 7 ] [Deng H.]College of Physics and Information Engineering, Institute of Micro-Nano Devices and Solar Cells, Fuzhou University, Fuzhou, 350108, China
  • [ 8 ] [Deng H.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou, 350108, China
  • [ 9 ] [Zhang C.]College of Physics and Information Engineering, Institute of Micro-Nano Devices and Solar Cells, Fuzhou University, Fuzhou, 350108, China
  • [ 10 ] [Zhang C.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou, 350108, China
  • [ 11 ] [Wang W.]College of Physics and Information Engineering, Institute of Micro-Nano Devices and Solar Cells, Fuzhou University, Fuzhou, 350108, China
  • [ 12 ] [Wang W.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou, 350108, China
  • [ 13 ] [Meng Q.]Key Laboratory for Renewable Energy, Chinese Academy of Sciences, Beijing Key, Laboratory for New Energy Materials and Devices, Institute of Physics, Beijing, 100190, China
  • [ 14 ] [Wu J.]College of Physics and Information Engineering, Institute of Micro-Nano Devices and Solar Cells, Fuzhou University, Fuzhou, 350108, China
  • [ 15 ] [Wu J.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou, 350108, China
  • [ 16 ] [Li D.]Key Laboratory for Renewable Energy, Chinese Academy of Sciences, Beijing Key, Laboratory for New Energy Materials and Devices, Institute of Physics, Beijing, 100190, China
  • [ 17 ] [Cheng S.]College of Physics and Information Engineering, Institute of Micro-Nano Devices and Solar Cells, Fuzhou University, Fuzhou, 350108, China
  • [ 18 ] [Cheng S.]Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China, Fuzhou, 350108, China

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Source :

Materials Today Physics

ISSN: 2542-5293

Year: 2024

Volume: 45

1 0 . 0 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 2

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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