Login | Cas Login
English| 简体中文| 繁体中文

  • Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
成果搜索

Advanced Search

author：

Xiao, Z. (Xiao, Z..) [1] | Wan, Z. (Wan, Z..) [2] | Zhang, J. (Zhang, J..) [3] | Jiang, J. (Jiang, J..) [4] | Li, D. (Li, D..) [5] | Shen, J. (Shen, J..) [6] | Dai, W. (Dai, W..) [7] | Li, Y. (Li, Y..) [8] | Wang, X. (Wang, X..) [9] | Zhang, Z. (Zhang, Z..) [10]

Indexed by：

Scopus

Abstract：

Photocatalytic　methane　conversion　into　liquid　oxygenates　using　O2　oxidants　provides　a　promising　approach　for　high-value　chemicals.　The　generation　of　reactive　oxygen　species　and　their　reaction　pathway　are　key　to　determine　the　oxygenate　selectivity.　Here,　an　interstitial　Zni　defect　ZnO　(ZnO(Zni))　is　developed　through　thermal　decomposition　of　the　ZnO2　precursor.　Zni　favors　the　O2　adsorption　at　a　terminal　adsorption　configuration　and　induces　effectively　the　conversion　O2　into　the　desired　•OOH　instead　of　•OH　for　improving　the　yield　and　selectivity　of　oxygenates.　For　comparison,　O2　adsorbed　in　a　lateral　configuration　tends　to　be　converted　into　excessive　•OH　on　the　typical　Au/ZnO.　As　a　result,　ZnO(Zni)　shows　the　liquid　oxygenates　yield　of　6080　μmol　g-1　with　98.6%　selectivity,　which　leads　to　10　times　lower　than　Au/ZnO　for　CO2　release　of　overoxidation.　This　work　provides　a　pathway　for　O2　adsorption　and　activation　to　regulate　the　photocatalytic　CH4　oxidation　conversion　into　liquid　oxygenates.　©　2024　American　Chemical　Society.

Keyword：

defects interstitial zinc methane conversion oxygen activation selectivity

Community：

  • [ 1 ] [Xiao Z.]State Key Lab of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 2 ] [Xiao Z.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 3 ] [Wan Z.]State Key Lab of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 4 ] [Wan Z.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 5 ] [Zhang J.]State Key Lab of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 6 ] [Zhang J.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 7 ] [Jiang J.]State Key Lab of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 8 ] [Jiang J.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 9 ] [Li D.]State Key Lab of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 10 ] [Li D.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 11 ] [Shen J.]State Key Lab of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 12 ] [Shen J.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 13 ] [Dai W.]State Key Lab of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 14 ] [Dai W.]Qingyuan Innovation Laboratory, Quanzhou, 362801, China
  • [ 15 ] [Dai W.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 16 ] [Li Y.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 17 ] [Wang X.]State Key Lab of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 18 ] [Wang X.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 19 ] [Zhang Z.]State Key Lab of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou, 350116, China
  • [ 20 ] [Zhang Z.]Qingyuan Innovation Laboratory, Quanzhou, 362801, China
  • [ 21 ] [Zhang Z.]College of Chemistry, Fuzhou University, Fuzhou, 350116, China

Reprint 's Address：

Email：

Show more details

Related Keywords：

Related Article：

Source ：

ACS Catalysis

ISSN： 2155-5435

Year： 2024

Issue： 12

Volume： 14

Page： 9104-9114

1 1 . 7 0 0

JCR@2023

CAS Journal Grade：1

Cited Count：

WoS CC Cited Count：

SCOPUS Cited Count：

ESI Highly Cited Papers on the List： 0 Unfold All

WanFang Cited Count：

Chinese Cited Count：

30 Days PV： 1

Affiliated Colleges：

Get Fulltext

DOI Library Discovery Baidu Scholar Search SCOPUS
Online/Total：516/10787185
Address：FZU Library(No.2 Xuyuan Road, Fuzhou, Fujian, PRC Post Code：350116) Contact Us：0591-22865326
Copyright：FZU Library Technical Support：Beijing Aegean Software Co., Ltd. 闽ICP备05005463号-1