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author:

Zhang, Z. (Zhang, Z..) [1] | Yao, A. (Yao, A..) [2] (Scholars:姚爱芳) | Raffa, P. (Raffa, P..) [3]

Indexed by:

Scopus

Abstract:

Conductive hydrogels have emerged as fascinating materials for flexible electronics because of their integrated conductivity, mechanical flexibility, and the possibility to introduce several smart functions. However, the swelling of hydrogels in aqueous environments significantly reduces their applicability where contact with water is unavoidable. In this study, a physically cross-linked composite hydrogel is proposed, that is transparent, highly stretchable, anti-swelling, capable of autonomous self-healing, adhesive, and anti-freezing. The hydrogel is synthesized through a simple one-step photopolymerization in a novel deep eutectic solvent (DES)/water system. Dynamic physical interactions, including hydrophobic interaction, hydrogen bonding, and electrostatic interactions, confer remarkable transparency (92%), self-healing capability (up to 94%), good adhesion to a wide array of substrates (91 to 199 kPa), high toughness (1.46 MJ m−3), excellent elongation at break (up to 2064%), and resistance to swelling in water (equilibrium swelling ratio of 3% in water for 30 days) even in solutions at different pH (pH 1–11), and in other solvents. The incorporation of a DES contributes to exceptional anti-freezing performance. The transparent sensor achieves multifunctional sensing and human motion detection with high sensitivity and stability. Notably, the sensor demonstrates information transmission underwater through stretching and pressing, showcasing its immense potential in underwater flexible devices. © 2024 The Author(s). Advanced Functional Materials published by Wiley-VCH GmbH.

Keyword:

conductive hydrogels flexible electronics self-healing swelling-resistant underwater sensing

Community:

  • [ 1 ] [Zhang Z.]Smart and Sustainable Polymeric Products, Engineering and Technology Institute Groningen (ENTEG), Faculty of Science and Engineering, University of Groningen, Nijenborgh 4, Groningen, 9747 AG, Netherlands
  • [ 2 ] [Yao A.]College of Biological Science and Engineering, Fuzhou University, Fuzhou, 350108, China
  • [ 3 ] [Raffa P.]Smart and Sustainable Polymeric Products, Engineering and Technology Institute Groningen (ENTEG), Faculty of Science and Engineering, University of Groningen, Nijenborgh 4, Groningen, 9747 AG, Netherlands

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Advanced Functional Materials

ISSN: 1616-301X

Year: 2024

Issue: 49

Volume: 34

1 8 . 5 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 1

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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