Combining Ti4(embonate)6 anionic cages and π-conjugated coordination cations for highly effective optical limiting - Details

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The　integration　of　anionic　Ti4L6　(L　=　embonate)　cages　and　π-conjugated　coordination　cations　into　ordered　structures　can　produce　high-performance　nonlinear　optical　(NLO)　materials.　More　specifically,　by　employing　Ti4L6　cages　for　assembly　with　mixed　N,N-chelated　and　P,P-chelated　type　conjugated　organic　ligands　and　Ag+　ions,　three　cage-based　structures　have　been　synthesized　and　structurally　characterized.　Among　them,　an　ion　pair　structure　with　strong　π-π　accumulation　exhibits　a　significant　third-order　NLO　response,　and　an　excellent　optical　limiting　effect　has　been　experimentally　verified.　This　work　provides　a　promising　material　for　NLO　applications.　©　2024　The　Royal　Society　of　Chemistry.

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Chelation Positive ions

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[ 1 ] [Yuan, Yuan]College of Chemistry, Fuzhou University, Fujian, Fuzhou; 350108, China
[ 2 ] [Yuan, Yuan]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou; 350002, China
[ 3 ] [Zhang, Dong-Hui]College of Chemistry, Fuzhou University, Fujian, Fuzhou; 350108, China
[ 4 ] [Zhang, Dong-Hui]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou; 350002, China
[ 5 ] [Li, Qiao-Hong]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou; 350002, China
[ 6 ] [Chen, Shu-Mei]College of Chemistry, Fuzhou University, Fujian, Fuzhou; 350108, China
[ 7 ] [He, Yan-Ping]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou; 350002, China
[ 8 ] [Zhang, Jian]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou; 350002, China

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Source ：

Chemical Communications

ISSN： 1359-7345

Year： 2024

Issue： 66

Volume： 60

Page： 8748-8751

4 . 3 0 0

JCR@2023

CAS Journal Grade：3

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ESI Highly Cited Papers on the List： 0 Unfold All

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30 Days PV： 6

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