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author:

Yang, Zhengwei (Yang, Zhengwei.) [1] | Lu, Haolin (Lu, Haolin.) [2] | Zhang, Yu (Zhang, Yu.) [3] | Yin, Baipeng (Yin, Baipeng.) [4] | Wang, Hong (Wang, Hong.) [5] | Gull, Sehrish (Gull, Sehrish.) [6] | Qin, Wei (Qin, Wei.) [7] | Chen, Yongsheng (Chen, Yongsheng.) [8] | Yao, Jiannian (Yao, Jiannian.) [9] | Zhang, Chuang (Zhang, Chuang.) [10] | Long, Guankui (Long, Guankui.) [11]

Indexed by:

EI Scopus SCIE

Abstract:

Chiral perovskites are considered as promising candidates for circularly polarized luminescence (CPL) light source, by attracting the broader scientific community for their applications in chiral optoelectronics and spintronics. However, it is still a great challenge to achieve both substantial photoluminescence asymmetry (gCPL) and high photoluminescence quantum yield (PLQY) simultaneously for high CPL brightness due to the limitations associated with magnetic transition dipole moments. Herein, this problem is overcome and achieve both large gCPL of 1.6x10-2 and PLQY of 56% in chiral perovskite through the magnetic element doping strategy. The substitution of Pb2+ ion with smaller magnetic Mn2+ ions shrinks the crystal lattice around [MnBr6]4- octahedra, amplifying the asymmetric distortion surrounding the Mn2+ ions. Moreover, the transition associated with Mn2+ ions can harvest the photoexcitation energy in chiral perovskites, and its spin-flipping characteristics enable highly efficient CPL from the d-d transition on Mn2+ energy levels. Furthermore, this magnetic element doping strategy is proven to be a universal tactic for enhancing CPL brightness as confirmed in a series of 1D- or 2D-chiral perovskites with various chiral ligands or halogens. The findings provide an in-depth understanding of the structure-property relationship in chiral perovskites toward chiral optoelectronic and spintronic applications. In this work, a universal strategy is demonstrated to enhance CPL performance through combination of enhancing chiral distortions and spin-flipping of the d-d transition. The unprecedented CPL Brightness, with a FM (PLQY x gCPL) of 9.0 x 10-3 is achieved in chiral 2-NEA2Pb0.8Mn0.2Br4, which is the highest value among all the chiral perovskite films reported at room temperature. image

Keyword:

chirality chiral perovskites circularly polarized luminescence energy transfer manganese dope

Community:

  • [ 1 ] [Yang, Zhengwei]Chinese Acad Sci, Inst Chem, Key Lab Photochem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
  • [ 2 ] [Zhang, Yu]Chinese Acad Sci, Inst Chem, Key Lab Photochem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
  • [ 3 ] [Yin, Baipeng]Chinese Acad Sci, Inst Chem, Key Lab Photochem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
  • [ 4 ] [Wang, Hong]Chinese Acad Sci, Inst Chem, Key Lab Photochem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
  • [ 5 ] [Yao, Jiannian]Chinese Acad Sci, Inst Chem, Key Lab Photochem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
  • [ 6 ] [Zhang, Chuang]Chinese Acad Sci, Inst Chem, Key Lab Photochem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China
  • [ 7 ] [Yang, Zhengwei]Univ Chinese Acad Sci, Beijing 100049, Peoples R China
  • [ 8 ] [Zhang, Yu]Univ Chinese Acad Sci, Beijing 100049, Peoples R China
  • [ 9 ] [Wang, Hong]Univ Chinese Acad Sci, Beijing 100049, Peoples R China
  • [ 10 ] [Lu, Haolin]Nankai Univ, Natl Inst Adv Mat, Sch Mat Sci & Engn, Tianjin Key Lab Rare Earth Mat & Applicat, Tianjin 300350, Peoples R China
  • [ 11 ] [Gull, Sehrish]Nankai Univ, Natl Inst Adv Mat, Sch Mat Sci & Engn, Tianjin Key Lab Rare Earth Mat & Applicat, Tianjin 300350, Peoples R China
  • [ 12 ] [Long, Guankui]Nankai Univ, Natl Inst Adv Mat, Sch Mat Sci & Engn, Tianjin Key Lab Rare Earth Mat & Applicat, Tianjin 300350, Peoples R China
  • [ 13 ] [Qin, Wei]Shandong Univ, Sch Phys, State Key Lab Crystal Mat, Jinan 250100, Peoples R China
  • [ 14 ] [Chen, Yongsheng]Nankai Univ, State Key Lab & Inst Elemento Organ Chem, Coll Chem, Ctr Nanoscale Sci & Technol, Tianjin 300071, Peoples R China
  • [ 15 ] [Yao, Jiannian]Fuzhou Univ, Inst Mol Engn Plus, Fuzhou 350108, Peoples R China

Reprint 's Address:

  • [Zhang, Chuang]Chinese Acad Sci, Inst Chem, Key Lab Photochem, Beijing Natl Lab Mol Sci, Beijing 100190, Peoples R China;;[Long, Guankui]Nankai Univ, Natl Inst Adv Mat, Sch Mat Sci & Engn, Tianjin Key Lab Rare Earth Mat & Applicat, Tianjin 300350, Peoples R China;;

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Source :

LASER & PHOTONICS REVIEWS

ISSN: 1863-8880

Year: 2024

Issue: 10

Volume: 18

9 . 8 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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