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author:

Lin, Liang (Lin, Liang.) [1] | Wu, Renkang (Wu, Renkang.) [2] | Zhuang, Yanping (Zhuang, Yanping.) [3] | Zhang, Yinggan (Zhang, Yinggan.) [4] | Xia, Li (Xia, Li.) [5] | Wang, Jin (Wang, Jin.) [6] | Zhang, Chengkun (Zhang, Chengkun.) [7] | Sa, Baisheng (Sa, Baisheng.) [8] (Scholars:萨百晟) | Luo, Qing (Luo, Qing.) [9] | Wang, Laisen (Wang, Laisen.) [10] | Lin, Jie (Lin, Jie.) [11] | Lin, Yingbin (Lin, Yingbin.) [12] | Peng, Dong-Liang (Peng, Dong-Liang.) [13] | Xie, Qingshui (Xie, Qingshui.) [14]

Indexed by:

EI Scopus SCIE

Abstract:

Sodium (Na) metal anodes receive significant attention due to their high theoretical specific energy and costeffectiveness. However, the high reactivity of Na foil anodes and the irregular surfaces have posed challenges to the operability and reliability of Na metals in battery applications. In the absence of inert environmental protection conditions, constructing a uniform, dense, and sodiophilic Na metal anode surface is crucial for homogenizing Na deposition, but remains less-explored. Herein, we fabricated a Tin (Sn) nanoparticle-assembled film conforming to separator pores, which provided ample space for accommodating volumetric expansion during the Na alloying process. Subsequently, a seamless Na-Sn alloy overlayer was formed and transferred onto the Na foil during Na plating through a separator-assisted technique, thereby overcoming conventional operational limitations of metallic Na. As compared to traditional volumetrically expanded cracked ones, the present autotransferable, highly sodiophilic, ion-conductive, and seamless Na-Sn alloy overlayer serves as uniform nucleation sites, thereby reducing nucleation and diffusion barriers and facilitating the compact deposition of metallic Na. Consequently, the autotransferable alloy layer enables a high average Coulombic efficiency of 99.9 % at 3.0 mA cm -2 and 3.0 mAh cm -2 in the half cells as well as minimal polarization overpotentials in symmetric cells, both during prolonged cycling 1200 h. Furthermore, the assembled Na||Sn-1.0h-PP||Na 3 V 2 (- PO 4 ) 3 @C@CNTs full cell delivers high capacity retention of 97.5 % after 200 cycles at a high cathodic mass loading.

Keyword:

Alloy interface layer Dendrite -free deposition Separator -assisted autotransfer Sodium metal anodes

Community:

  • [ 1 ] [Lin, Liang]Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Coll Mat, Fujian Key Lab Surface & Interface Engn High Perfo, Xiamen 361005, Peoples R China
  • [ 2 ] [Wu, Renkang]Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Coll Mat, Fujian Key Lab Surface & Interface Engn High Perfo, Xiamen 361005, Peoples R China
  • [ 3 ] [Zhuang, Yanping]Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Coll Mat, Fujian Key Lab Surface & Interface Engn High Perfo, Xiamen 361005, Peoples R China
  • [ 4 ] [Zhang, Yinggan]Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Coll Mat, Fujian Key Lab Surface & Interface Engn High Perfo, Xiamen 361005, Peoples R China
  • [ 5 ] [Xia, Li]Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Coll Mat, Fujian Key Lab Surface & Interface Engn High Perfo, Xiamen 361005, Peoples R China
  • [ 6 ] [Zhang, Chengkun]Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Coll Mat, Fujian Key Lab Surface & Interface Engn High Perfo, Xiamen 361005, Peoples R China
  • [ 7 ] [Luo, Qing]Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Coll Mat, Fujian Key Lab Surface & Interface Engn High Perfo, Xiamen 361005, Peoples R China
  • [ 8 ] [Wang, Laisen]Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Coll Mat, Fujian Key Lab Surface & Interface Engn High Perfo, Xiamen 361005, Peoples R China
  • [ 9 ] [Lin, Jie]Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Coll Mat, Fujian Key Lab Surface & Interface Engn High Perfo, Xiamen 361005, Peoples R China
  • [ 10 ] [Peng, Dong-Liang]Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Coll Mat, Fujian Key Lab Surface & Interface Engn High Perfo, Xiamen 361005, Peoples R China
  • [ 11 ] [Xie, Qingshui]Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Coll Mat, Fujian Key Lab Surface & Interface Engn High Perfo, Xiamen 361005, Peoples R China
  • [ 12 ] [Wang, Jin]Xiamen Univ, Pen Tung Sah Inst Micronano Sci & Technol, Xiamen 361005, Peoples R China
  • [ 13 ] [Sa, Baisheng]Fuzhou Univ, Coll Mat Sci & Engn, Multiscale Computat Mat Facil, Fuzhou 350100, Peoples R China
  • [ 14 ] [Lin, Yingbin]Fujian Normal Univ, Coll Phys & Energy, Fujian Prov Solar Energy Convers & Energy Storage, Fuzhou 350117, Peoples R China

Reprint 's Address:

  • [Peng, Dong-Liang]Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Coll Mat, Fujian Key Lab Surface & Interface Engn High Perfo, Xiamen 361005, Peoples R China;;[Xie, Qingshui]Xiamen Univ, State Key Lab Phys Chem Solid Surfaces, Coll Mat, Fujian Key Lab Surface & Interface Engn High Perfo, Xiamen 361005, Peoples R China;;

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Source :

JOURNAL OF COLLOID AND INTERFACE SCIENCE

ISSN: 0021-9797

Year: 2024

Volume: 670

Page: 215-222

9 . 4 0 0

JCR@2023

Cited Count:

WoS CC Cited Count: 1

SCOPUS Cited Count: 1

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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