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author:

Zhang, Lin (Zhang, Lin.) [1] | Zhu, Xiaolong (Zhu, Xiaolong.) [2] | Wang, Guanyao (Wang, Guanyao.) [3] | Xu, Gang (Xu, Gang.) [4] | Wu, Minghong (Wu, Minghong.) [5] (Scholars:吴明红) | Liu, Hua-Kun (Liu, Hua-Kun.) [6] | Dou, Shi-Xue (Dou, Shi-Xue.) [7] | Wu, Chao (Wu, Chao.) [8]

Indexed by:

SCIE

Abstract:

Sodium metal is regarded as one of the most prospective next-generation anodes material owing to its high theoretical capacity, low redox potential, low cost, and natural abundance. Its most notable problem is the dendrite growth during Na plating/striping, which causes not only the safety concern but also the generation of inactive Na. Here, it is demonstrated that 2D carbon nanosheets embedded by bismuth nanoparticles (NPs) (denoted as Bi subset of CNs) serve as a robust nucleation buffer layer to endow the sodium metal anodes (SMAs) with high Coulombic efficiencies (CEs) and dendrite-free deposition during long-term cycling. The embedded Bi nanoparticles significantly reduce the nucleation barrier through the "sodiophilic" Na-Bi alloy. Meanwhile, the carbon frameworks effectively circumvent the gradual failure of those Na-Bi nucleation sites. As a result, the metallic Na on the Bi subset of CNs nucleation layer is repeatedly plated/stripped for nearly 7700 h (1287 cycles) at 3 mA h cm(-2) with an average CE of 99.92%. Moreover, the Na||Na symmetric cells with the Bi subset of CNs buffer layer are stably plated/stripped for 4000 h at 1 mA cm(-2) and 1 mA h cm(-2). It is found that the cycling stability is closely related to the Na utilization of SMAs and current rate.

Keyword:

dendrite&#8208 free deposition nucleation layers plating sodium metal anodes stripping

Community:

  • [ 1 ] [Zhang, Lin]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 2 ] [Zhu, Xiaolong]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 3 ] [Wang, Guanyao]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 4 ] [Wu, Chao]Shanghai Univ, Sch Environm & Chem Engn, Shanghai 200444, Peoples R China
  • [ 5 ] [Xu, Gang]Shanghai Univ, Shanghai Appl Radiat Inst, Shanghai 200444, Peoples R China
  • [ 6 ] [Wu, Minghong]Shanghai Univ, Shanghai Appl Radiat Inst, Shanghai 200444, Peoples R China
  • [ 7 ] [Liu, Hua-Kun]Univ Wollongong, Australian Inst Innovat Mat, Inst Superconducting & Elect Mat, Wollongong, NSW 2522, Australia
  • [ 8 ] [Dou, Shi-Xue]Univ Wollongong, Australian Inst Innovat Mat, Inst Superconducting & Elect Mat, Wollongong, NSW 2522, Australia
  • [ 9 ] [Wu, Chao]Univ Wollongong, Australian Inst Innovat Mat, Inst Superconducting & Elect Mat, Wollongong, NSW 2522, Australia

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Source :

SMALL

ISSN: 1613-6810

Year: 2021

Issue: 12

Volume: 17

1 5 . 1 5 3

JCR@2021

1 3 . 0 0 0

JCR@2023

JCR Journal Grade:1

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 50

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 4

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