Poor　water　removal　of　low-molecular-weight　anthropogenic　contaminants　is　always　a　key　problem　in　low-pressure　membrane　filtration　process.　In　this　work,　we　successfully　designed　and　fabricated　a　novel　cobalt-based　bimetallic　catalytic　ceramic　membrane　(CoFe2O4@CM-2)　with　peroxymonosulfate　(PMS)　activation　and　membrane　filtration　dual　functionality,　employing　a　facile　impregnation-filtration-calcination　method.　The　resulting　CoFe2O4@CM-2/PMS　filtration　system　was　specifically　tailored　for　the　removal　of　carbamazepine　(CBZ).　Our　results　demonstrate　that　the　CoFe2O4@CM-2/PMS　system　achieved　efficient　removal　of　CBZ　from　contaminated　waters.　Under　optimal　conditions　(PMS　dosage　of　0.5　mM　and　an　operating　flux　of　40　L·m−2·h−1),　the　CoFe2O4@CM-2/PMS　system　exhibited　remarkable　CBZ　removal　efficiency,　reaching　up　to　96.5　%.　This　efficiency　was　32.2　and　19.3　times　higher　than　that　achieved　by　ceramic　membrane　filtration　alone　and　PMS　treatment　alone,　respectively.　Additionally,　the　CoFe2O4@CM-2/PMS　system　facilitated　37.0　%　mineralization　of　CBZ　and　up　to　87　%　utilization　of　PMS　in　the　permeate.　Furthermore,　the　CoFe2O4@CM-2/PMS　system　demonstrated　robust　performance,　removing　over　91　%　of　CBZ　across　a　pH　range　of　3–9　and　maintaining　stability　stability　in　the　presence　of　humic　acid　(HA)　interference.　Its　exceptional　anti-fouling　ability　effectively　mitigates　membrane　flux　loss　compared　to　single　membrane　filtration　process.　Quenching　test,　electron　paramagnetic　resonance　(EPR),　and　X-ray　photoelectron　spectroscopy　(XPS)　analyses　revealed　that　1O2,　SO4-∙　and　·OH　were　the　primary　active　substances　in　the　system,　while　the　redox　cycle　of　Co2+/Co3+　played　a　crucial　role　in　PMS　activation.　Moreover,　the　presence　of　iron　(Fe)　in　the　CoFe₂O₄@CM-2　expedited　the　Co2+/Co3+　cycle　and　enhanced　PMS　activation.　This　study　introduces　an　innovative　approach　for　fabricating　ceramic　membranes　with　catalytic　degradation　capabilities　for　organic　pollutants　and　suggests　promising　avenues　for　integrating　separation　and　advanced　oxidation　processes　(AOPs)　in　future　applications.　©　2024　Elsevier　B.V.