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author:

Fu, Yu-Gang (Fu, Yu-Gang.) [1] | Li, Yi-Han (Li, Yi-Han.) [2] | Lu, Qiu-Feng (Lu, Qiu-Feng.) [3] (Scholars:吕秋丰)

Indexed by:

EI Scopus SCIE

Abstract:

Nickel-cobalt layered double hydroxide (NiCo-LDH) has received much attention in the field of supercapacitor electrodes due to its multiple oxidation states and good electrochemical activity. However, NiCo-LDH often suffers from structural instability and low conductivity in practical applications. In this study, sea urchin-like structural NiCo-LDH coated cobalt-nitrogen co-doped carbon (NiCo-LDH@Co-NC-x) electrode materials were prepared by in situ growth of NiCo-LDH on the surface of cobalt-nitrogen co-doped carbon nanosheets (Co-NC) using a one-step hydrothermal method. The results show that the NiCo-LDH@Co-NC-2 electrode material exhibits excellent electrochemical performance, its specific capacitance is up to 1909 F g- 1 at a current density of 1 A g- 1, and capacitance retention of 69.5 % (only 26.2 % for NiCo-LDH) can be achieved after 10,000 cycles at a current density of 10 A g- 1. This is because the abundant and uniformly distributed Co nanoparticles on Co-NC provide nucleation sites for the in-situ growth of NiCo-LDH, effectively improving the interface binding between Co-NC and NiCo-LDH, enhancing the structural stability of NiCo-LDH, and ensuring highly efficient electron transport throughout the NiCo-LDH@Co-NC-2 electrode. An asymmetric supercapacitor (NiCo-LDH@Co-NC-2// AC) was further assembled with NiCo-LDH@Co-NC-2 and activated carbon (AC) as positive and negative electrodes, respectively, achieving an energy density as high as 36.8 Wh kg- 1 at a power density of 750 W kg- 1. These findings suggest that the NiCo-LDH@Co-NC-2 composite can be a promising candidate for highperformance supercapacitor electrode.

Keyword:

Carbon nanosheets Nickel-cobalt layered double hydroxide Supercapacitor

Community:

  • [ 1 ] [Fu, Yu-Gang]Fuzhou Univ, Coll Mat Sci & Engn, 2 Wulongjiang North Ave, Fuzhou 350108, Peoples R China
  • [ 2 ] [Li, Yi-Han]Fuzhou Univ, Coll Mat Sci & Engn, 2 Wulongjiang North Ave, Fuzhou 350108, Peoples R China
  • [ 3 ] [Lu, Qiu-Feng]Fuzhou Univ, Coll Mat Sci & Engn, 2 Wulongjiang North Ave, Fuzhou 350108, Peoples R China

Reprint 's Address:

  • [Lu, Qiu-Feng]Fuzhou Univ, Coll Mat Sci & Engn, 2 Wulongjiang North Ave, Fuzhou 350108, Peoples R China;;

Email:

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Source :

JOURNAL OF ENERGY STORAGE

ISSN: 2352-152X

Year: 2024

Volume: 100

8 . 9 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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