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Abstract:
Transition metal dichalcogenides (TMDs) have enormous commercial potential as anode materials for all-solidstate lithium-ion batteries (ASSLIBs). Herein, the copper sulfides (CuS) with a hierarchical nanosphere structure are designed through a facile one-step solvothermal synthetic route. When employed as an anode for ASSLIBs, the CuS hierarchical nanospheres (hn-CuS) exhibited a high capacity of 350 mA h g(-1) after 50 cycles at a current density of 250 mA g(-1) and an outstanding rate capability. The unique three-dimensional (3D) structure of hn-CuS plays an important role in alleviating the volume expansion, thus obtaining excellent electrochemical properties. Moreover, ex-situ X-ray diffraction was used to investigate the possible kinetics and reaction mechanism of the hn-CuS anode. This work inspired a new promise for preparing the other TMDs as anode materials for ASSLIBs with high performance.
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JOURNAL OF ENERGY STORAGE
ISSN: 2352-152X
Year: 2024
Volume: 100
8 . 9 0 0
JCR@2023
Cited Count:
SCOPUS Cited Count: 1
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 0
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