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author:

Wei, Sheng-Li (Wei, Sheng-Li.) [1] | Yang, Yan-Ling (Yang, Yan-Ling.) [2] | Chen, Jin-Geng (Chen, Jin-Geng.) [3] | Shi, Xiao-Lei (Shi, Xiao-Lei.) [4] | Sun, Yu (Sun, Yu.) [5] | Li, Peng (Li, Peng.) [6] | Tian, Xue-Feng (Tian, Xue-Feng.) [7] | Chen, Hua-Jun (Chen, Hua-Jun.) [8] | Luo, Zhao (Luo, Zhao.) [9] | Chen, Zhi-Gang (Chen, Zhi-Gang.) [10]

Indexed by:

EI Scopus SCIE

Abstract:

Owing to the abundant reserves and low cost, sodium-ion batteries (SIBs) have garnered unprecedented attention. However, their widespread adoption is hindered by the scarcity of alternative anodes with fast-charging capability and high stability. To overcome this challenge, a fast-charging SIB anode, N-doped Bi/BiOCl embedded in a carbon framework (Bi/BiOCl@NC) with a fast Na+ transport channel and ultra-high structural stability, is developed. During cycling in ether electrolyte, Bi/BiOCl@NC undergoes a remarkable transformation into a 3D porous skeleton, which significantly reduces the Na+ transport pathway and accommodates volume changes. By employing density functional theory calculations to simulate the storage behavior of Na+ in the structure, Bi/BiOCl@NC is theoretically characterized to have a low Na+ transport barrier (0.056 eV) and outstanding electronic conductivity. Such unique characteristics induce Bi/BiOCl@NC anode to have an ultra-high Na+ storage capacity of 410 mAhg-1 at 20 Ag-1 and exhibit outstanding cycling stability with over 2300 cycles at 10 Ag-1. This study provides a rational scenario for the fast-charging anode design and will enlighten more advanced research to promote the exploitation of SIBs. A fast-charging SIB anode, N-doped Bi/BiOCl embedded in a carbon framework, with a fast Na+ transport channel, is developed. Density functional theory calculations confirm that the anode is theoretically characterized to have a low Na+ transport barrier (0.056 eV) and outstanding electronic conductivity. image

Keyword:

anode Bi/BiOCl@NC ether electrolyte fast-charge sodium-ion batteries

Community:

  • [ 1 ] [Wei, Sheng-Li]Shaanxi Univ Sci & Technol, Sch Mat Sci & Engn, Shaanxi Key Lab Green Preparat & Functionalizat In, Xian 710021, Peoples R China
  • [ 2 ] [Yang, Yan-Ling]Shaanxi Univ Sci & Technol, Sch Mat Sci & Engn, Shaanxi Key Lab Green Preparat & Functionalizat In, Xian 710021, Peoples R China
  • [ 3 ] [Chen, Jin-Geng]Shaanxi Univ Sci & Technol, Sch Mat Sci & Engn, Shaanxi Key Lab Green Preparat & Functionalizat In, Xian 710021, Peoples R China
  • [ 4 ] [Sun, Yu]Shaanxi Univ Sci & Technol, Sch Mat Sci & Engn, Shaanxi Key Lab Green Preparat & Functionalizat In, Xian 710021, Peoples R China
  • [ 5 ] [Luo, Zhao]Shaanxi Univ Sci & Technol, Sch Mat Sci & Engn, Shaanxi Key Lab Green Preparat & Functionalizat In, Xian 710021, Peoples R China
  • [ 6 ] [Shi, Xiao-Lei]Queensland Univ Technol, Sch Chem & Phys, ARC Res Hub Zeroemission Power Generat Carbon Neut, Ctr Mat Sci, Brisbane, QLD 4000, Australia
  • [ 7 ] [Chen, Zhi-Gang]Queensland Univ Technol, Sch Chem & Phys, ARC Res Hub Zeroemission Power Generat Carbon Neut, Ctr Mat Sci, Brisbane, QLD 4000, Australia
  • [ 8 ] [Li, Peng]Fuzhou Univ, Coll Chem, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Peoples R China
  • [ 9 ] [Tian, Xue-Feng]Guangdong Songshan Polytech, Sch Adv Mfg, Shaoguan 512126, Peoples R China
  • [ 10 ] [Chen, Hua-Jun]Luoyang Inst Sci & Technol, Sch Environm & Chem, Luoyang 471023, Peoples R China

Reprint 's Address:

  • [Yang, Yan-Ling]Shaanxi Univ Sci & Technol, Sch Mat Sci & Engn, Shaanxi Key Lab Green Preparat & Functionalizat In, Xian 710021, Peoples R China;;[Sun, Yu]Shaanxi Univ Sci & Technol, Sch Mat Sci & Engn, Shaanxi Key Lab Green Preparat & Functionalizat In, Xian 710021, Peoples R China;;[Chen, Zhi-Gang]Queensland Univ Technol, Sch Chem & Phys, ARC Res Hub Zeroemission Power Generat Carbon Neut, Ctr Mat Sci, Brisbane, QLD 4000, Australia;;

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Source :

ADVANCED ENERGY MATERIALS

ISSN: 1614-6832

Year: 2024

Issue: 37

Volume: 14

2 4 . 4 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 2

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