• Complex
  • Title
  • Keyword
  • Abstract
  • Scholars
  • Journal
  • ISSN
  • Conference
成果搜索

author:

Yan, Shuai (Yan, Shuai.) [1] | Li, Zhonglin (Li, Zhonglin.) [2] | Liu, Yongyao (Liu, Yongyao.) [3] | Wei, Yifan (Wei, Yifan.) [4] | Ji, Zhenyu (Ji, Zhenyu.) [5] | Chen, Cheng (Chen, Cheng.) [6] | Wu, Mingyan (Wu, Mingyan.) [7]

Indexed by:

EI Scopus SCIE

Abstract:

Phthalocyanine (Pc), a macrocyclic aromatic compound, has attracted extensive attention in energy storage due to its large pi-conjugated structure and abundant nitrogen sites. However, the poor solubility of Pc monomers leads to rigorous polymerization conditions, which hinder the application and development of Pc-based polymers. Herein, 1,4,5,8,9,11-hexaazatriphenylenehexacarbonitrile (HAT(CN)6) is used as a precursor to construct Pc-based conjugated polymers (Pc-COPs) via a molten salt assisted strategy. The physical-chemical properties of the resulting Pc-COPs at different synthesis temperatures were systematically studied, which indicates that Pc-COP-350 (at the synthesis temperature of 350 degrees C) exhibits complete polymerization while maintaining the redox activity of the active centers. As the cathode material for aqueous zinc-ion batteries, Pc-COP-350 exhibited the best electrochemical performance, achieving a specific capacity of 269 mA h g(-1) at 0.05 A g(-1). The Coulombic efficiency is up to nearly 100% even after long cycles at a current density of 1 A g(-1). This work provides a pathway for designing and synthesizing Pc-based macrocyclic compounds.

Keyword:

aqueous zinc-ion batteries cathode materials conjugated organic polymers defect molten saltstrategy

Community:

  • [ 1 ] [Yan, Shuai]Fuzhou Univ, Coll Chem, Dept Chem, Fuzhou 350108, Peoples R China
  • [ 2 ] [Yan, Shuai]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
  • [ 3 ] [Li, Zhonglin]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
  • [ 4 ] [Liu, Yongyao]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
  • [ 5 ] [Wei, Yifan]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
  • [ 6 ] [Ji, Zhenyu]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
  • [ 7 ] [Chen, Cheng]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
  • [ 8 ] [Wu, Mingyan]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China
  • [ 9 ] [Wu, Mingyan]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Fujian, Peoples R China
  • [ 10 ] [Li, Zhonglin]Dongguan Univ Technol, Sch Environm & Civil Engn, Dongguan 523808, Guangdong, Peoples R China

Reprint 's Address:

  • [Li, Zhonglin]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China;;[Wu, Mingyan]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Peoples R China;;[Wu, Mingyan]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Fujian, Peoples R China;;[Li, Zhonglin]Dongguan Univ Technol, Sch Environm & Civil Engn, Dongguan 523808, Guangdong, Peoples R China;;

Show more details

Related Keywords:

Source :

ACS APPLIED POLYMER MATERIALS

ISSN: 2637-6105

Year: 2024

Issue: 20

Volume: 6

Page: 12823-12831

4 . 5 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

Online/Total:355/10024630
Address:FZU Library(No.2 Xuyuan Road, Fuzhou, Fujian, PRC Post Code:350116) Contact Us:0591-22865326
Copyright:FZU Library Technical Support:Beijing Aegean Software Co., Ltd. 闽ICP备05005463号-1