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Abstract:
Zinc(Zn) metal anodes have been extensively investigated in aqueousZn-ion batteries (AZIBs). Nevertheless, severe dendrite issues causedby uneven ion diffusion and Zn deposition greatly influence the stabilityand safety of AZIBs. Herein, a novel three-electrode tubular cellassembled from simple materials is constructed for both electrochemicalmeasurement and visual characterization. Measured by the tubular cell,a water-in-salt electrolyte (WiSE) exhibits excellent ionic conductivity(33.29 mS cm(-1)) and reduced corrosivity, which isprepared by incorporating cellulose and polyethylene glycol (PEG)into concentrated zinc chloride (ZnCl2) solution. The resultsreveal that the functional groups of cellulose and PEG in WiSE canregulate the solvation structure of Zn2+, thereby alleviatingconsecutive side reactions and inhibiting the formation of byproducts.The inherent ion channels formed by the polymer chains and the physicalbarriers constructed by PEG on the Zn surface further facilitatedthe uniform deposition of Zn2+ along the (002) crystalplane, enabling the Zn symmetric battery to achieve an ultralong cyclelife of 1000 h at a current density of 2 mA cm(-2). Zinc (Zn) metal anodes have been extensivelyinvestigatedin aqueous Zn-ion batteries (AZIBs). A novel three-electrode tubularcell assembled from simple materials is constructed for both electrochemicalmeasurement and visual characterization.
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ACS SUSTAINABLE CHEMISTRY & ENGINEERING
ISSN: 2168-0485
Year: 2023
Issue: 28
Volume: 11
Page: 10311-10323
7 . 1
JCR@2023
7 . 1 0 0
JCR@2023
ESI Discipline: CHEMISTRY;
ESI HC Threshold:39
JCR Journal Grade:1
CAS Journal Grade:2
Cited Count:
WoS CC Cited Count: 2
SCOPUS Cited Count: 2
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
Affiliated Colleges: