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author:

Miao, Yu (Miao, Yu.) [1] | Yang, Wanting (Yang, Wanting.) [2] | Ding, Xuemin (Ding, Xuemin.) [3] | Min, Jiarui (Min, Jiarui.) [4] | Guo, Bao (Guo, Bao.) [5] | Chen, Xiangxiang (Chen, Xiangxiang.) [6] | Yu, Chun (Yu, Chun.) [7]

Abstract:

Lead is an indispensable non-ferrous metal for industrial development. As primary galena(PbS) resources are being exhausted, the utilization of lead oxide ore resources have become increasingly important. Compared with the conventional lead oxide surface sulfidation flotation method by NaHS dosing in the pulp, the roasting sulfidation pre-treatment method has the characteristics of high efficiency and suitable for various types of ores. In this paper, we firstly demonstrate that pyrite(FeS2) can provide a sulfurous atmosphere to convert cerussite(PbCO3) into galena(PbS) through thermodynamic calculations. Then, the reaction conditions were optimized through the roasting sulfidation conditions such as the contact mode, time and temperature of the reaction, and the sulfidation mechanism of cerussite at high temperature roasting was studied by using XRF, XRD, SEM and XPS. It was clarified that the sulfidation of cerussite was progressed by reacting with sulfur-based atmosphere from the surface layer to form PbS, and then gradually penetrating into the inner layer until PbS was completely generated, and the recovery rate was increased from 14.95 % to >80 % after optimization.

Keyword:

Cerussite Energy saving and carbon reduction Flotation Sulfidation mechanism Sulfidation roasting

Community:

  • [ 1 ] [Miao, Yu]Fuzhou Univ, Sch Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 2 ] [Miao, Yu]Fuzhou Univ, Sch Zijin Geol & Min, Fuzhou 350108, Peoples R China
  • [ 3 ] [Yang, Wanting]Fuzhou Univ, Sch Zijin Geol & Min, Fuzhou 350108, Peoples R China
  • [ 4 ] [Ding, Xuemin]Fuzhou Univ, Sch Zijin Geol & Min, Fuzhou 350108, Peoples R China
  • [ 5 ] [Min, Jiarui]Fuzhou Univ, Sch Zijin Geol & Min, Fuzhou 350108, Peoples R China
  • [ 6 ] [Guo, Bao]Fuzhou Univ, Sch Zijin Geol & Min, Fuzhou 350108, Peoples R China
  • [ 7 ] [Chen, Xiangxiang]Fuzhou Univ, Sch Zijin Geol & Min, Fuzhou 350108, Peoples R China
  • [ 8 ] [Miao, Yu]Changchun Gold Res Inst Co Ltd, Changchun 130000, Peoples R China
  • [ 9 ] [Yu, Chun]Strait Inst Flexible Elect, SIFE, Future Technol, Fuzhou 350117, Peoples R China
  • [ 10 ] [Yu, Chun]Fujian Key Lab Flexible Elect, Fuzhou 350117, Peoples R China
  • [ 11 ] [Yu, Chun]Fujian Normal Univ, Fuzhou 350117, Peoples R China
  • [ 12 ] [Yu, Chun]Strait Lab Flexible Elect SLoFE, Fuzhou 350117, Peoples R China

Reprint 's Address:

  • [Guo, Bao]Fuzhou Univ, Sch Zijin Geol & Min, Fuzhou 350108, Peoples R China;;[Chen, Xiangxiang]Fuzhou Univ, Sch Zijin Geol & Min, Fuzhou 350108, Peoples R China;;[Yu, Chun]Strait Inst Flexible Elect, SIFE, Future Technol, Fuzhou 350117, Peoples R China;;[Yu, Chun]Fujian Key Lab Flexible Elect, Fuzhou 350117, Peoples R China;;[Yu, Chun]Fujian Normal Univ, Fuzhou 350117, Peoples R China;;[Yu, Chun]Strait Lab Flexible Elect SLoFE, Fuzhou 350117, Peoples R China;;

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Source :

CHEMICAL ENGINEERING JOURNAL ADVANCES

ISSN: 2666-8211

Year: 2025

Volume: 21

5 . 5 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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