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author:

Yu, Chun (Yu, Chun.) [1] | Zhu, Liangzhen (Zhu, Liangzhen.) [2] | Ding, Xuemin (Ding, Xuemin.) [3] | Guo, Bao (Guo, Bao.) [4] (Scholars:郭宝)

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Scopus SCIE

Abstract:

Compared to copper sulfide minerals with good floatability in copper ore beneficiation, copper oxide minerals exhibit poor floatability but increasing reserves as refractory copper resources. Sulfidation of copper oxide minerals by adding Na2S into the pulp is a common strategy to increase their floatability. In this work, sulfidation roasting as a pretreatment method was proposed to increase the floatability of malachite using xanthate as the collector. Roasting was conducted at 500-600 degrees C for 3-120 min using pyrite as the sulfur source and coal to control oxygen partial pressure (PO2), which plays a crucial role in sulfidation reactions. Thermodynamic factors and experimental observations, including roasting product characterization and roasting kinetics analysis, were considered to optimize the roasting parameters with minimized energy and material consumption. It was found that 84.5% flotation recovery can be achieved by roasting malachite at 500 degrees C for 6 min. Microanalysis shows that sulfidation occurs homogeneously across the bulk particle because of porous structure of the raw mineral. The SO2 gas species, as a pyrite oxidation product and sulfur carrier in the roasting system, diffuse into malachite mineral particles and sulfidize copper oxide to chalcocite and digenite.

Keyword:

Community:

  • [ 1 ] [Yu, Chun]Fujian Normal Univ, Strait Inst Flexible Elect SIFE Future Technol, Fujian Key Lab Flexible Elect, Fuzhou 350117, Peoples R China
  • [ 2 ] [Zhu, Liangzhen]Fujian Normal Univ, Strait Inst Flexible Elect SIFE Future Technol, Fujian Key Lab Flexible Elect, Fuzhou 350117, Peoples R China
  • [ 3 ] [Yu, Chun]Strait Lab Flexible Elect SLoFE, Fuzhou 350117, Fujian, Peoples R China
  • [ 4 ] [Zhu, Liangzhen]Strait Lab Flexible Elect SLoFE, Fuzhou 350117, Fujian, Peoples R China
  • [ 5 ] [Ding, Xuemin]Fuzhou Univ, Zijin Sch Min & Geol, Fuzhou 350108, Fujian, Peoples R China
  • [ 6 ] [Guo, Bao]Fuzhou Univ, Zijin Sch Min & Geol, Fuzhou 350108, Fujian, Peoples R China

Reprint 's Address:

  • 郭宝

    [Guo, Bao]Fuzhou Univ, Zijin Sch Min & Geol, Fuzhou 350108, Fujian, Peoples R China

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Source :

JOM

ISSN: 1047-4838

Year: 2025

Issue: 4

Volume: 77

Page: 2444-2452

2 . 1 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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