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Compared to copper sulfide minerals with good floatability in copper ore beneficiation, copper oxide minerals exhibit poor floatability but increasing reserves as refractory copper resources. Sulfidation of copper oxide minerals by adding Na2S into the pulp is a common strategy to increase their floatability. In this work, sulfidation roasting as a pretreatment method was proposed to increase the floatability of malachite using xanthate as the collector. Roasting was conducted at 500-600 degrees C for 3-120 min using pyrite as the sulfur source and coal to control oxygen partial pressure (PO2), which plays a crucial role in sulfidation reactions. Thermodynamic factors and experimental observations, including roasting product characterization and roasting kinetics analysis, were considered to optimize the roasting parameters with minimized energy and material consumption. It was found that 84.5% flotation recovery can be achieved by roasting malachite at 500 degrees C for 6 min. Microanalysis shows that sulfidation occurs homogeneously across the bulk particle because of porous structure of the raw mineral. The SO2 gas species, as a pyrite oxidation product and sulfur carrier in the roasting system, diffuse into malachite mineral particles and sulfidize copper oxide to chalcocite and digenite.
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JOM
ISSN: 1047-4838
Year: 2025
Issue: 4
Volume: 77
Page: 2444-2452
2 . 1 0 0
JCR@2023
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SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 3
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