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author:

Lin, Yi (Lin, Yi.) [1] | Dong, Gaoming (Dong, Gaoming.) [2] | Lin, Hang (Lin, Hang.) [3] | Wang, Bo (Wang, Bo.) [4] | Wang, Pengfei (Wang, Pengfei.) [5] | Xu, Ju (Xu, Ju.) [6] | Cheng, Yao (Cheng, Yao.) [7] | Xiong, Yan (Xiong, Yan.) [8] | Wang, Yuansheng (Wang, Yuansheng.) [9]

Indexed by:

EI Scopus SCIE

Abstract:

The rise of laser diode (LD)-driven phosphor-converted near-infrared (NIR) lighting sources, offering unparalleled advantages in terms of brightness and imaging resolution, is hindered by a scarcity of color converters possessing desired properties. Herein, we synthesized a new Ca2YScAl2Si2O12:Cr3+ (CYSAS:Cr3+) broadband NIR-emissive garnet phosphor with a full width at half maximum (FWHM) of 165 nm, attributed to the presence of Cr3+ ions at two distinct crystallographic sites in CYSAS as verified through spectroscopic analyses. With the aid of a rapid infrared firing technique pioneered in our lab, a phosphor-in-glass film (PiGF) composite was then successfully sintered onto a sapphire plate (SP), showing minimal interfacial reactions during co-sintering and thus retention of luminescent properties. The saturation behavior of luminescence under intense blue laser irradiation was meticulously examined across different excitation modes. By incorporating a "phosphor wheel", we achieved a peak NIR output power of 2626 mW (@17 W or 21.7 W mm-2), surpassing the majority of previously reported phosphor-converted lighting sources. The demonstration experiments highlighted the potential applications of the engineered laser-driven NIR light source in non-destructive detection, quantitative analysis of organic components, night vision and biological imaging.

Keyword:

Community:

  • [ 1 ] [Lin, Yi]Fuzhou Univ, Coll Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 2 ] [Dong, Gaoming]Fuzhou Univ, Coll Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 3 ] [Xiong, Yan]Hubei Univ Technol, Hubei Prov Key Lab Green Mat Light Ind, Wuhan 430068, Hubei, Peoples R China
  • [ 4 ] [Lin, Yi]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 5 ] [Dong, Gaoming]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 6 ] [Lin, Hang]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 7 ] [Lin, Hang]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, Fuzhou 350002, Fujian, Peoples R China
  • [ 8 ] [Wang, Pengfei]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, Fuzhou 350002, Fujian, Peoples R China
  • [ 9 ] [Xu, Ju]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, Fuzhou 350002, Fujian, Peoples R China
  • [ 10 ] [Cheng, Yao]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, Fuzhou 350002, Fujian, Peoples R China
  • [ 11 ] [Wang, Yuansheng]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, Fuzhou 350002, Fujian, Peoples R China
  • [ 12 ] [Wang, Bo]Wuyi Univ, Sch Appl Phys & Mat, Jiangmen 529020, Guangdong, Peoples R China

Reprint 's Address:

  • [Lin, Hang]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China;;[Lin, Hang]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, Fuzhou 350002, Fujian, Peoples R China;;[Wang, Yuansheng]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Key Lab Nanomat, Fuzhou 350002, Fujian, Peoples R China;;

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Source :

JOURNAL OF MATERIALS CHEMISTRY C

ISSN: 2050-7526

Year: 2025

Issue: 8

Volume: 13

Page: 4020-4030

5 . 7 0 0

JCR@2023

Cited Count:

WoS CC Cited Count: 1

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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