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author:

Chen, Ming (Chen, Ming.) [1] | Liu, Feng-Ming (Liu, Feng-Ming.) [2] | Zhao, Ming-Yang (Zhao, Ming-Yang.) [3] | Qian, Xing (Qian, Xing.) [4] (Scholars:钱兴) | Yuan, Zhong-Yong (Yuan, Zhong-Yong.) [5] | Wan, Rong (Wan, Rong.) [6] | Li, Chun-Sheng (Li, Chun-Sheng.) [7] | Zhang, Xing (Zhang, Xing.) [8] | Wang, Shuo (Wang, Shuo.) [9]

Indexed by:

EI Scopus SCIE

Abstract:

Fe3N nanocrystals embedded in cracked N-doped carbon nanotubes (Fe3N@NCNT) with a cowpea-like shape are innovatively prepared by metal-catalyzed graphitization and nitridization processes based on melamine and FeC2O4 precursor. The new in-situ synthesis strategy is proved to be effective to open the NCNT using a migratory metal carbide nanocatalyst via expansion effect and fabricate a metal nitride embedded NCNT with fully active ingredients. The detailed tip-growth mechanism of cracked NCNT with latitudinal-longitudinal graphene layers is studied by in-situ XRD analysis of the phase evolution of melamine and FeC2O4, and ex-situ SEM/TEM investigation of the topography correlation of NCNT and Fe3C floating catalyst. The Fe3N@NCNT microclews based anodes have a moderate carbon content of 35.45 wt%, electroactive NCNT conductive network, abundant microcracks and an open short-cavity system, showing a stable discharge capacity of 667 mAh g-1 at 0.1C, outstanding rate capability of 448 mAh g-1 at 5C and remarkable long-term cycling stability of 546 mAh g-1 after 600 cycles at 1C. The combined good electronic/ionic conductivity of cracked NCNT and robust mechanical stability of geometrically confined Fe3N nanoparticles contribute to the excellent redox activities, stabilized solid-electrolyte-interphase film and cycling durability of Fe3N@NCNT.

Keyword:

Anodes Carbon nanotubes Growth mechanism Iron nitrides Lithium-ion batteries

Community:

  • [ 1 ] [Chen, Ming]Xinyang Normal Univ, Coll Chem & Chem Engn, Xinyang 464000, Peoples R China
  • [ 2 ] [Liu, Feng-Ming]Xinyang Normal Univ, Coll Chem & Chem Engn, Xinyang 464000, Peoples R China
  • [ 3 ] [Zhao, Ming-Yang]Xinyang Normal Univ, Coll Chem & Chem Engn, Xinyang 464000, Peoples R China
  • [ 4 ] [Wan, Rong]Xinyang Normal Univ, Coll Chem & Chem Engn, Xinyang 464000, Peoples R China
  • [ 5 ] [Zhang, Xing]Xinyang Normal Univ, Coll Chem & Chem Engn, Xinyang 464000, Peoples R China
  • [ 6 ] [Wang, Shuo]Xinyang Normal Univ, Coll Chem & Chem Engn, Xinyang 464000, Peoples R China
  • [ 7 ] [Qian, Xing]Fuzhou Univ, Coll Chem Engn, Fuzhou 350116, Peoples R China
  • [ 8 ] [Yuan, Zhong-Yong]Nankai Univ, Sch Mat Sci & Engn, Tianjin 300071, Peoples R China
  • [ 9 ] [Li, Chun-Sheng]Suzhou Univ Sci & Technol, Sch Chem & Life Sci, Suzhou 215009, Peoples R China

Reprint 's Address:

  • [Chen, Ming]Xinyang Normal Univ, Coll Chem & Chem Engn, Xinyang 464000, Peoples R China

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Source :

CARBON

ISSN: 0008-6223

Year: 2024

Volume: 230

1 0 . 5 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 5

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