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author:

Zhang, Yanbing (Zhang, Yanbing.) [1] | Wang, Xie (Wang, Xie.) [2] | Liang, Banglei (Liang, Banglei.) [3] | Ren, Haibo (Ren, Haibo.) [4] | Zhang, Xiaoxia (Zhang, Xiaoxia.) [5] | Liu, Xingye (Liu, Xingye.) [6] | Zheng, Weijie (Zheng, Weijie.) [7] | Liu, Xuelian (Liu, Xuelian.) [8] (Scholars:刘雪莲) | Zhang, Huazhi (Zhang, Huazhi.) [9] | Zhang, Xiang (Zhang, Xiang.) [10]

Indexed by:

EI Scopus SCIE

Abstract:

A series of catalytic filters (Mn-Fe-CeOx/PPS) with satisfactory NO conversion and physical properties were synthesized by the redox method. The Mn-Fe-Ce ternary catalyst system and corresponding oxidation-reduction equation were established by using the low-valent oxidation characteristics of cerium and iron to react with high-valent manganese capable of reduction. Furthermore, the optimal catalytic filter synthesized under the guidance of reaction principles has excellent physicochemical properties such as high NO conversion (100 % at 180 degrees C), high stability, low loading capacity (66.8 g/m2), and strong binding ability, making it suitable for complex operating conditions. Particularly, in the Mn-Fe-Ce ternary catalyst system, the coexistence of Ce4+ and Ce3+ causes the formation of surface oxygen vacancies, uneven local charge distribution and additional chemisorbed oxygen, which are conducive to the low-temperature selective catalytic reduction (L-T SCR) reaction. Meanwhile, there are also high valence Mn4+ and Fe3+ in catalyst system, which can promote the oxidation of NO and further improve the L-T SCR reaction.

Keyword:

L-T SCR reaction Mn-Fe-CeOx/PPS catalytic filters NO conversion Oxidation-reduction equation Reaction principles

Community:

  • [ 1 ] [Zhang, Yanbing]Henan Univ Urban Construct, Coll Mat & Chem Engn, Pingdingshan 467000, Peoples R China
  • [ 2 ] [Liang, Banglei]Henan Univ Urban Construct, Coll Mat & Chem Engn, Pingdingshan 467000, Peoples R China
  • [ 3 ] [Ren, Haibo]Henan Univ Urban Construct, Coll Mat & Chem Engn, Pingdingshan 467000, Peoples R China
  • [ 4 ] [Liu, Xingye]Fuzhou Univ, Coll Adv Mfg, Jinjiang 362251, Peoples R China
  • [ 5 ] [Zheng, Weijie]Fuzhou Univ, Coll Adv Mfg, Jinjiang 362251, Peoples R China
  • [ 6 ] [Liu, Xuelian]Fuzhou Univ, Coll Adv Mfg, Jinjiang 362251, Peoples R China
  • [ 7 ] [Wang, Xie]Anqing Normal Univ, Sch Chem & Chem Engn, Anqing 246011, Peoples R China
  • [ 8 ] [Zhang, Xiaoxia]North China Elect Power Univ, Coll Environm Sci & Engn, Beijing 102206, Peoples R China
  • [ 9 ] [Zhang, Huazhi]Key Lab Fine Chem Applicat Technol Luzhou, Luzhou 646099, Peoples R China
  • [ 10 ] [Zhang, Xiang]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China
  • [ 11 ] [Zhang, Xiang]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fujian Prov Key Lab Nanomat, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

Reprint 's Address:

  • 郑伟杰 刘雪莲

    [Zheng, Weijie]Fuzhou Univ, Coll Adv Mfg, Jinjiang 362251, Peoples R China;;[Liu, Xuelian]Fuzhou Univ, Coll Adv Mfg, Jinjiang 362251, Peoples R China;;[Zhang, Huazhi]Key Lab Fine Chem Applicat Technol Luzhou, Luzhou 646099, Peoples R China;;[Zhang, Xiang]Chinese Acad Sci, Fujian Inst Res Struct Matter, CAS Key Lab Design & Assembly Funct Nanostruct, Fuzhou 350002, Fujian, Peoples R China

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Source :

ENVIRONMENTAL TECHNOLOGY & INNOVATION

ISSN: 2352-1864

Year: 2025

Volume: 37

6 . 7 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count: 2

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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