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Abstract:
A series of catalytic filters (Mn-Fe-CeOx/PPS) with satisfactory NO conversion and physical properties were synthesized by the redox method. The Mn-Fe-Ce ternary catalyst system and corresponding oxidation-reduction equation were established by using the low-valent oxidation characteristics of cerium and iron to react with high-valent manganese capable of reduction. Furthermore, the optimal catalytic filter synthesized under the guidance of reaction principles has excellent physicochemical properties such as high NO conversion (100 % at 180 degrees C), high stability, low loading capacity (66.8 g/m2), and strong binding ability, making it suitable for complex operating conditions. Particularly, in the Mn-Fe-Ce ternary catalyst system, the coexistence of Ce4+ and Ce3+ causes the formation of surface oxygen vacancies, uneven local charge distribution and additional chemisorbed oxygen, which are conducive to the low-temperature selective catalytic reduction (L-T SCR) reaction. Meanwhile, there are also high valence Mn4+ and Fe3+ in catalyst system, which can promote the oxidation of NO and further improve the L-T SCR reaction.
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ENVIRONMENTAL TECHNOLOGY & INNOVATION
ISSN: 2352-1864
Year: 2025
Volume: 37
6 . 7 0 0
JCR@2023
Cited Count:
SCOPUS Cited Count: 2
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 0