The　commercial　application　of　flexible　lithium-sulfur　batteries　is　severely　hindered　by　poor　conductivity,　low　active　material　loading,　polysulfide　shuttle　effects,　and　sluggish　redox　kinetics.　Herein,　we　developed　a　unique　three-dimensional　(3D)　conductive　network　framework　decorated　with　NiCo　bimetallic　particles.　The　3D　porous　carbon　conductive　network　skeleton　formed　by　crosslinked　carbon　nanotubes　effectively　mitigates　the　volume　expansion　of　sulfur　and　accommodates　abundant　active　materials　for　high　discharge　capacity.　Meanwhile,　the　NiCo　bimetallic　combines　the　catalytic　role　of　Ni　in　sulfur　reduction　and　Co　in　sulfur　oxidation　to　achieve　improved　kinetics　of　the　entire　conversion　of　sulfur.　Most　importantly,　the　sulfur　host　synergizes　the　conducting　CNTs　and　catalytically　active　bimetallic,　increasing　conductance　and　accelerating　reaction　kinetics,　resulting　in　a　significant　improvement　in　rate　performance.　Consequently,　the　cells　equipped　with　NiCo@CNT-S　cathode　exhibit　a　low-capacity　decay　rate　of　only　0.07　%　per　cycle　over　400　cycles　at　1C,　and　an　ultra-high　initial　specific　capacity　of　1030　mAh　g−1　at　a　high　rate　of　5C.　Notably,　the　pouch　cell　assembled　with　the　NiCo@CNT-S　could　deliver　a　high　areal　discharge　capacity　of　8.2　mAh　cm−2　at　0.1C,　with　a　sulfur　loading　of　7.1　mg　cm−2　and　an　E/S　ratio　of　7.1　μL　mg−1.　This　work　provides　novel　structural　design　and　mechanism　insights　for　the　practical　application　of　flexible　lithium-sulfur　batteries.　©　2025　Elsevier　B.V.