We　present　here　a　catalytic　enantioconvergent　amination　of　alcohols　for　efficient　access　to　chiral　C2-and　C3-substituted　benzomorpholines.　The　racemic　amino　alcohol　substrates　of　different　substitution　patterns,　which　are　readily　available　from　a　common　precursor,　can　be　converted　to　the　enantioenriched　heterocycles　in　a　highly　atom-　and　step-economical　fashion.　In　particular,　an　unprecedented　asymmetric　amination　of　racemic　primary　alcohols　via　dynamic　kinetic　resolution　is　achieved　under　cooperative　iridium/iron　catalysis,　resulting　in　highly　enantioenriched　C2-substituted　benzomorpholines　that　are　difficult　to　access　otherwise.　©　2025　Chinese　Chemical　Society.　All　rights　reserved.