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The CuMgZrOx oxide catalysts were employed with economical 2-PrOH as the hydrogen donor for catalytic transfer hydrogenation of ethyl levulinate (EL) to gamma-valerolactone (GVL). The cost-effective Cu1Mg1.15Zr2Ox catalyst exhibited excellent physicochemical properties, with 99.8% EL conversion and 88.0% GVL yield. Studies have shown that sufficient basic sites of the catalyst, along with the maintenance of the Cu2+/Cu+ state rather than Cu0, are crucial for achieving high GVL yields. Optimization of the substrate-to-hydrogen donor ratio (1:3), along with recycling tests and characterization, demonstrated excellent activity (99.5% EL conversion and 90.0% GVL yield) and cycle stability for the Cu1Mg1.15Zr2Ox catalyst, highlighting its strong potential for practical applications. The mechanism for GVL production from EL via the metal hydride as the dominant route was proposed based on rigorous experimental studies and in-depth characterization. Substrate scope evaluation showed that the Cu1Mg1.15Zr2Ox catalyst also exhibited outstanding activity in converting methyl levulinate and butyl levulinate to GVL.
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JOURNAL OF CATALYSIS
ISSN: 0021-9517
Year: 2025
Volume: 444
6 . 5 0 0
JCR@2023
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 1