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author:

Zhang, Liangqing (Zhang, Liangqing.) [1] (Scholars:张良清) | Xiao, Hong (Xiao, Hong.) [2] | Zhou, Ben (Zhou, Ben.) [3] | Hong, Yonglin (Hong, Yonglin.) [4] | Wu, Qiaomei (Wu, Qiaomei.) [5] | Qiu, Jiarong (Qiu, Jiarong.) [6] | Chen, Jianfeng (Chen, Jianfeng.) [7]

Indexed by:

EI Scopus SCIE

Abstract:

The CuMgZrOx oxide catalysts were employed with economical 2-PrOH as the hydrogen donor for catalytic transfer hydrogenation of ethyl levulinate (EL) to gamma-valerolactone (GVL). The cost-effective Cu1Mg1.15Zr2Ox catalyst exhibited excellent physicochemical properties, with 99.8% EL conversion and 88.0% GVL yield. Studies have shown that sufficient basic sites of the catalyst, along with the maintenance of the Cu2+/Cu+ state rather than Cu0, are crucial for achieving high GVL yields. Optimization of the substrate-to-hydrogen donor ratio (1:3), along with recycling tests and characterization, demonstrated excellent activity (99.5% EL conversion and 90.0% GVL yield) and cycle stability for the Cu1Mg1.15Zr2Ox catalyst, highlighting its strong potential for practical applications. The mechanism for GVL production from EL via the metal hydride as the dominant route was proposed based on rigorous experimental studies and in-depth characterization. Substrate scope evaluation showed that the Cu1Mg1.15Zr2Ox catalyst also exhibited outstanding activity in converting methyl levulinate and butyl levulinate to GVL.

Keyword:

CuMgZrOx gamma-Valerolactone Levulinate esters Metal hydride route Stability

Community:

  • [ 1 ] [Zhang, Liangqing]Fuzhou Univ, Sch Adv Mfg, Jinjiang 362251, Peoples R China
  • [ 2 ] [Xiao, Hong]Fuzhou Univ, Sch Adv Mfg, Jinjiang 362251, Peoples R China
  • [ 3 ] [Zhou, Ben]Fuzhou Univ, Sch Adv Mfg, Jinjiang 362251, Peoples R China
  • [ 4 ] [Hong, Yonglin]Fuzhou Univ, Sch Adv Mfg, Jinjiang 362251, Peoples R China
  • [ 5 ] [Wu, Qiaomei]Fuzhou Univ, Sch Adv Mfg, Jinjiang 362251, Peoples R China
  • [ 6 ] [Qiu, Jiarong]Fuzhou Univ, Sch Adv Mfg, Jinjiang 362251, Peoples R China
  • [ 7 ] [Chen, Jianfeng]Fuzhou Univ, Sch Adv Mfg, Jinjiang 362251, Peoples R China
  • [ 8 ] [Zhang, Liangqing]Fuzhou Univ, Dev Ctr Sci & Educ Pk, Jinjiang 362251, Peoples R China
  • [ 9 ] [Qiu, Jiarong]Fuzhou Univ, Dev Ctr Sci & Educ Pk, Jinjiang 362251, Peoples R China

Reprint 's Address:

  • 邱佳容

    [Qiu, Jiarong]Fuzhou Univ, Sch Adv Mfg, Jinjiang 362251, Peoples R China

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Source :

JOURNAL OF CATALYSIS

ISSN: 0021-9517

Year: 2025

Volume: 444

6 . 5 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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