Indexed by:
Abstract:
Mesoporous carbon has been proven to be an effective sulfur-loading host for cathode materials in lithium-sulfur batteries (LSBs) due to its abundant pore structure and flexibility in modification. In this work, a threedimensional ultrathin-wall mesoporous carbon (UMC) was created by directly pyrolyzing a mixture of petroleum residue and aluminum isopropoxide. Afterword, CoS2/N-doped UMC (NUMC) samples were synthesized and used as sulfur carriers to fabricate composite materials for LSBs. The graphene-like layers and porous structure of UMC promote excellent conductivity and rapid charge transfer, facilitating the complete impregnation of cobalt and sulfur sources into the UMC. The prepared CoS2/NUMC samples effectively inhibit the shuttle effect of polysulfides and promote the adsorption and conversion of lithium polysulfides, thereby improving the redox kinetics of the battery. Electrochemical tests showed that the CoS2/NUMC@S composite material, prepared with a mass ratio of Co(NO3)2 & sdot;6H2O to UMC of 0.5:1, had an initial capacity of 1324.74 mAh g- 1 at 0.1 C, and the capacity remained at 533.3 mAh g- 1 even at a high rate of 3 C, demonstrating excellent reversibility and high-rate performance. After 1000 cycles, the capacity decay per cycle was only 0.047 %, indicating good cycling stability. Therefore, the composite electrode provides an effective approach for developing high-performance LSBs.
Keyword:
Reprint 's Address:
Email:
Version:
Source :
JOURNAL OF ALLOYS AND COMPOUNDS
ISSN: 0925-8388
Year: 2025
Volume: 1020
5 . 8 0 0
JCR@2023
Cited Count:
SCOPUS Cited Count:
ESI Highly Cited Papers on the List: 0 Unfold All
WanFang Cited Count:
Chinese Cited Count:
30 Days PV: 1
Affiliated Colleges: