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author:

Yang, An-Cang (Yang, An-Cang.) [1] | Lu, Yao-Ping (Lu, Yao-Ping.) [2] | Zhang, Bin (Zhang, Bin.) [3] | Duan, Yong-Hua (Duan, Yong-Hua.) [4] | Ma, Li-Shi (Ma, Li-Shi.) [5] | Zheng, Shan-Ju (Zheng, Shan-Ju.) [6] | Peng, Ming-Jun (Peng, Ming-Jun.) [7] | Li, Meng-Nie (Li, Meng-Nie.) [8] | Xu, Zhi-Hang (Xu, Zhi-Hang.) [9]

Indexed by:

Scopus SCIE

Abstract:

The construction of intermetallic compounds (IMCs) connection layers with special compositions by adding small amounts of alloying elements has been proven to be an effective strategy for improving the reliability of electronic component interconnect. However, the synergistic effect mechanism of multi-component alloy compositions on the growth behavior of IMCs is not clear. Herein, we successfully prepared a new quaternary alloy solder with a composition of Sn-0.7Cu-0.175Pt-0.025Al (wt%) using the high-throughput screening (HTS) method. The results showed that it possesses excellent welding performance with an inhibition rate over 40% on the growth of IMCs layers. For Cu6Sn5, the co-doping of Al and Pt not only greatly improves its thermodynamic stability, but also effectively suppresses the phase transition. Meanwhile, the co-doping of Al and Pt also significantly delays the generation time of Kirkendall defects. The substitution sites of Al and Pt in Cu6Sn5 have been explored using atomic resolution imaging and advanced data informatics, indicating that Al and Pt preferentially substitute Sn and Cu atoms, respectively, to generate (Cu, Pt)6(Sn, Al)5. A one-dimensional (1D) kinetic model of the IMCs layer growth at the Sn solder/Cu substrate interface was derived and validated, and the results showed that the error of the derived mathematical model is less than 5%. Finally, the synergistic mechanism of Al and Pt co-doping on the growth rate of Cu6Sn5 was further elucidated. This work provides a feasible route for the design and development of multi-component alloy solders. (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(IMCs)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic).(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)IMCs(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic).(sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(HTS)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)Sn-0.7Cu-0.175Pt-0.025Al (wt%)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)IMCs(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)40%.(sic)(sic)Cu6Sn5(sic)(sic), (sic)Al(sic)Pt(sic)(sic)(sic)(sic)(sic)Cu6Sn5(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic).(sic)(sic)(sic)(sic), Al(sic)Pt(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic) Kirkendall (sic)(sic)(sic)(sic)(sic)(sic)(sic).(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)Al(sic)Pt(sic)eta-Cu6Sn5(sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)Al(sic)Pt(sic)(sic)(sic)(sic)(sic)(sic)Sn(sic)Cu(sic)(sic)(sic)(sic)eta-(Cu, Pt)6(Sn, Al)5.(sic)(sic)(sic)Sn(sic)(sic)/Cu(sic)(sic)(sic)(sic)(sic)IMCs(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic) 5%.(sic)(sic), (sic)(sic)(sic)(sic)(sic)(sic)Al(sic)Pt(sic)(sic)(sic)(sic) Cu6Sn5 (sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic).(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic)(sic).

Keyword:

Growth kinetic models HTS IMCs layer Sn-based solder Synergistic effect

Community:

  • [ 1 ] [Yang, An-Cang]Kunming Univ Sci & Technol, Fac Mat Sci & Engn, Yunnan Key Lab Integrated Computat Mat Engn Adv Li, Kunming 650093, Peoples R China
  • [ 2 ] [Zhang, Bin]Kunming Univ Sci & Technol, Fac Mat Sci & Engn, Yunnan Key Lab Integrated Computat Mat Engn Adv Li, Kunming 650093, Peoples R China
  • [ 3 ] [Duan, Yong-Hua]Kunming Univ Sci & Technol, Fac Mat Sci & Engn, Yunnan Key Lab Integrated Computat Mat Engn Adv Li, Kunming 650093, Peoples R China
  • [ 4 ] [Ma, Li-Shi]Kunming Univ Sci & Technol, Fac Mat Sci & Engn, Yunnan Key Lab Integrated Computat Mat Engn Adv Li, Kunming 650093, Peoples R China
  • [ 5 ] [Zheng, Shan-Ju]Kunming Univ Sci & Technol, Fac Mat Sci & Engn, Yunnan Key Lab Integrated Computat Mat Engn Adv Li, Kunming 650093, Peoples R China
  • [ 6 ] [Peng, Ming-Jun]Kunming Univ Sci & Technol, Fac Mat Sci & Engn, Yunnan Key Lab Integrated Computat Mat Engn Adv Li, Kunming 650093, Peoples R China
  • [ 7 ] [Li, Meng-Nie]Kunming Univ Sci & Technol, Fac Mat Sci & Engn, Yunnan Key Lab Integrated Computat Mat Engn Adv Li, Kunming 650093, Peoples R China
  • [ 8 ] [Lu, Yao-Ping]Fuzhou Univ, Coll Phys & Informat Engn, Fuzhou 350108, Peoples R China
  • [ 9 ] [Xu, Zhi-Hang]Hong Kong Polytech Univ, Res Inst Smart Energy, Dept Appl Phys, Hong Kong 999077, Peoples R China

Reprint 's Address:

  • [Duan, Yong-Hua]Kunming Univ Sci & Technol, Fac Mat Sci & Engn, Yunnan Key Lab Integrated Computat Mat Engn Adv Li, Kunming 650093, Peoples R China;;[Ma, Li-Shi]Kunming Univ Sci & Technol, Fac Mat Sci & Engn, Yunnan Key Lab Integrated Computat Mat Engn Adv Li, Kunming 650093, Peoples R China;;[Zheng, Shan-Ju]Kunming Univ Sci & Technol, Fac Mat Sci & Engn, Yunnan Key Lab Integrated Computat Mat Engn Adv Li, Kunming 650093, Peoples R China;;[Peng, Ming-Jun]Kunming Univ Sci & Technol, Fac Mat Sci & Engn, Yunnan Key Lab Integrated Computat Mat Engn Adv Li, Kunming 650093, Peoples R China

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Source :

RARE METALS

ISSN: 1001-0521

Year: 2025

Issue: 6

Volume: 44

Page: 4208-4225

9 . 6 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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