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author:

Fang, Lan (Fang, Lan.) [1] | Luo, Dengfeng (Luo, Dengfeng.) [2] | Zhang, Jing (Zhang, Jing.) [3] | Wang, Fukang (Wang, Fukang.) [4] | Zhang, Jiayang (Zhang, Jiayang.) [5] | Zheng, Zheheng (Zheng, Zheheng.) [6] | Xu, Zhiqun (Xu, Zhiqun.) [7] | Huang, Guobin (Huang, Guobin.) [8]

Indexed by:

EI Scopus SCIE

Abstract:

The commercial applications of lead halide perovskites are limited by their adverse environmental hazards and intrinsic instability. One promising strategy to mitigate the Pb2+ content is the doping of X2+ transition metal ions into cesium lead halide CsPbX3 (where X = Cl, Br, I) perovskite nanocrystals (PNCs). In this study, an ultrafast high-power ultrasonic synthesis method is employed to ensure uniform nucleation and growth of codoped (Zn, Mn): CsPbCl3 PNCs. Various analytical techniques are utilized to investigate the phase purity, microstructure, chemical composition, and photo-luminescence properties of the co-doped PNCs. Density functional theory (DFT) calculations reveal that the significantly enhanced optical performance of co-doped (Zn, Mn): CsPbCl3 PNCs is primarily due to the increased formation energy resulting from the successful incorporation of Zn2+ into Mn-doped CsPbCl3 PNCs, without introducing new defect states. Additionally, the co-doped (Zn, Mn): CsPbCl3 PNCs exhibit high sensitivity and selectivity in detecting Cu2+ ions. Our findings propose a novel approach for tuning the optical properties of co-doped (Zn, Mn): CsPbCl3 PNCs, highlighting their potential for applications in fluorescence sensors.

Keyword:

Co-doped Cu 2+detection DFT calculations Perovskite nanocrystals

Community:

  • [ 1 ] [Fang, Lan]Suzhou Chien Shiung Inst Technol, Taicang 215411, Peoples R China
  • [ 2 ] [Zhang, Jiayang]Suzhou Chien Shiung Inst Technol, Taicang 215411, Peoples R China
  • [ 3 ] [Xu, Zhiqun]Suzhou Chien Shiung Inst Technol, Taicang 215411, Peoples R China
  • [ 4 ] [Luo, Dengfeng]Peng Cheng Lab, Shenzhen 518055, Peoples R China
  • [ 5 ] [Luo, Dengfeng]Southern Univ Sci & Technol, Dept Elect & Elect Engn, Shenzhen 518055, Peoples R China
  • [ 6 ] [Zhang, Jing]China Pharmaceut Univ, Sch Engn, Dept Pharmaceut Engn, Nanjing 211198, Peoples R China
  • [ 7 ] [Wang, Fukang]Chinese Acad Sci, Shanghai Adv Res Inst, Shanghai 201210, Peoples R China
  • [ 8 ] [Zheng, Zheheng]Fuzhou Univ, Inst Food Safety & Environm Monitoring, Fuzhou 350108, Peoples R China
  • [ 9 ] [Huang, Guobin]Fuzhou Univ, Inst Food Safety & Environm Monitoring, Fuzhou 350108, Peoples R China

Reprint 's Address:

  • 胥智群 黄国斌

    [Xu, Zhiqun]Suzhou Chien Shiung Inst Technol, Taicang 215411, Peoples R China;;[Huang, Guobin]Fuzhou Univ, Inst Food Safety & Environm Monitoring, Fuzhou 350108, Peoples R China

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Source :

OPTICAL MATERIALS

ISSN: 0925-3467

Year: 2025

Volume: 161

3 . 8 0 0

JCR@2023

CAS Journal Grade:3

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 3

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