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author:

Zhang, Wenze (Zhang, Wenze.) [1] | Duan, Yukun (Duan, Yukun.) [2] | Chi, Xiaopeng (Chi, Xiaopeng.) [3] (Scholars:迟晓鹏) | Tan, Wen (Tan, Wen.) [4] (Scholars:谭文) | Weng, Wei (Weng, Wei.) [5] (Scholars:翁威) | Zhong, Shuiping (Zhong, Shuiping.) [6] (Scholars:衷水平)

Indexed by:

EI Scopus SCIE

Abstract:

In the zinc production industry using Mn-rich zinc ore, substantial quantities of anodic slime are generated during electrolytic zinc production, containing - 40 % Mn and - 3 % Pb. While a valuable secondary resource, this material poses environmental risks as solid waste. Conventional reductive leaching methods rely on costly reductants and generate high carbon emissions. This study introduces a process utilizing flue gas from zinc plants as a reductant, achieving 92 % Mn leaching efficiency while simultaneously extracting 25 % Sr and fixing 92 % SO2 as sulfate in solution. Kinetic analysis shows a mixed control model with an activation energy of 13.83 kJ/ mol, with reaction rates further enhanced by optimizing gas inlet design. The MnSO4-rich leachate is processed into battery-grade MnSO4 powder, and Sr is recovered as SrCO3, suitable for use as an additive in electrolytic zinc processes. Additionally, NaOH consumption for flue gas desulfurization decreases significantly from 2.14 kg to 0.17 kg per Nm3. Economic evaluation indicates reagent costs represent only 2 % of the total value of MnSO4 and SrCO3 products, offering a sustainable pathway for anodic slime utilization and SO2 mitigation in zinc smelting.

Keyword:

Anodic slime Desulfurization Hazardous solid wastes Manganese

Community:

  • [ 1 ] [Zhang, Wenze]Fuzhou Univ, Sch Mat Sci & Engn, Fuzhou 350108, Peoples R China
  • [ 2 ] [Duan, Yukun]Fuzhou Univ, Zijin Sch Geol & Min, Fuzhou 350108, Peoples R China
  • [ 3 ] [Chi, Xiaopeng]Fuzhou Univ, Zijin Sch Geol & Min, Fuzhou 350108, Peoples R China
  • [ 4 ] [Tan, Wen]Fuzhou Univ, Zijin Sch Geol & Min, Fuzhou 350108, Peoples R China
  • [ 5 ] [Weng, Wei]Fuzhou Univ, Zijin Sch Geol & Min, Fuzhou 350108, Peoples R China
  • [ 6 ] [Zhong, Shuiping]Fuzhou Univ, Zijin Sch Geol & Min, Fuzhou 350108, Peoples R China
  • [ 7 ] [Chi, Xiaopeng]Fuzhou Univ, Fujian Key Lab Green Extract & High Value Utilizat, Fuzhou 350108, Peoples R China
  • [ 8 ] [Tan, Wen]Fuzhou Univ, Fujian Key Lab Green Extract & High Value Utilizat, Fuzhou 350108, Peoples R China
  • [ 9 ] [Weng, Wei]Fuzhou Univ, Fujian Key Lab Green Extract & High Value Utilizat, Fuzhou 350108, Peoples R China
  • [ 10 ] [Zhong, Shuiping]Fuzhou Univ, Fujian Key Lab Green Extract & High Value Utilizat, Fuzhou 350108, Peoples R China
  • [ 11 ] [Zhong, Shuiping]Zijin Min Grp Co Ltd, Longyan 364200, Peoples R China

Reprint 's Address:

  • 翁威 衷水平

    [Weng, Wei]Fuzhou Univ, Zijin Sch Geol & Min, Fuzhou 350108, Peoples R China;;[Zhong, Shuiping]Fuzhou Univ, Zijin Sch Geol & Min, Fuzhou 350108, Peoples R China;;[Weng, Wei]Fuzhou Univ, Fujian Key Lab Green Extract & High Value Utilizat, Fuzhou 350108, Peoples R China;;[Zhong, Shuiping]Fuzhou Univ, Fujian Key Lab Green Extract & High Value Utilizat, Fuzhou 350108, Peoples R China;;[Zhong, Shuiping]Zijin Min Grp Co Ltd, Longyan 364200, Peoples R China

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Source :

SEPARATION AND PURIFICATION TECHNOLOGY

ISSN: 1383-5866

Year: 2025

Volume: 366

8 . 2 0 0

JCR@2023

CAS Journal Grade:2

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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