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author:

Rong, Hao (Rong, Hao.) [1] | Xu, Xinqi (Xu, Xinqi.) [2] | Yao, Jia-Yu (Yao, Jia-Yu.) [3] | Fan, Qingshun (Fan, Qingshun.) [4] | Zhang, Haoyu (Zhang, Haoyu.) [5] | Xu, Haojie (Xu, Haojie.) [6] | Luo, Junhua (Luo, Junhua.) [7] | Chen, Qiushui (Chen, Qiushui.) [8] (Scholars:陈秋水) | Sun, Zhihua (Sun, Zhihua.) [9]

Indexed by:

Scopus SCIE

Abstract:

Flexible scintillator screens characterized by high spatial resolution, low cost, and a simple fabrication process are in significant demand for applications in medical diagnosis and industrial detection. Here, we have demonstrated a new Mn2+-doped two-dimensional (2D) Ruddlesden-Popper type perovskite, (4-tert-butylbenzylamine)(2)PbBr4:Mn, serving as a highly efficient scintillator candidate. Doping with Mn2+ induces a spin-forbidden internal transition (T-4(1g) -> (6)A(1g)) that enhances the energy-transfer efficiency from the strongly bound excitons of the host material to the d electrons of the Mn2+ ions, ultimately leading to intense orange-red emission. This process enhances the photoluminescence quantum yield of (4-tert-butylbenzylamine)(2)PbBr4 (1) and decreases its self-absorption. Therefore, at the optimal Mn2+-doping concentration, 1:8.4%Mn2+ demonstrates a high light yield of 21,532 Ph/MeV and a low detection limit of 198.19 nGy(air) s(-1), exceeding the performance of a commercial bismuth germanium oxide (BGO) scintillator. Furthermore, we combined ultrafine powders of 1:8.4%Mn2+ with poly(dimethylsiloxane) to fabricate flexible scintillator films. With the optimal film thickness and mass percentage of 1:8.4%Mn2+, the scintillator films achieve their maximum spatial resolution of 17.3 lp mm(-1). The above results indicate that the exceptional flexible scintillation imaging performance of 1:8.4%Mn2+ effectively addresses the shortcomings of current commercial scintillators, thereby providing a new option for the scintillator family.

Keyword:

2D perovskite flexible scintillator screen imaging Mn2+ doping scintillator

Community:

  • [ 1 ] [Rong, Hao]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Funct Crystals & Devices, Fuzhou 350002, Fujian, Peoples R China
  • [ 2 ] [Yao, Jia-Yu]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Funct Crystals & Devices, Fuzhou 350002, Fujian, Peoples R China
  • [ 3 ] [Fan, Qingshun]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Funct Crystals & Devices, Fuzhou 350002, Fujian, Peoples R China
  • [ 4 ] [Zhang, Haoyu]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Funct Crystals & Devices, Fuzhou 350002, Fujian, Peoples R China
  • [ 5 ] [Xu, Haojie]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Funct Crystals & Devices, Fuzhou 350002, Fujian, Peoples R China
  • [ 6 ] [Luo, Junhua]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Funct Crystals & Devices, Fuzhou 350002, Fujian, Peoples R China
  • [ 7 ] [Sun, Zhihua]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Funct Crystals & Devices, Fuzhou 350002, Fujian, Peoples R China
  • [ 8 ] [Rong, Hao]Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China
  • [ 9 ] [Xu, Xinqi]Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China
  • [ 10 ] [Yao, Jia-Yu]Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China
  • [ 11 ] [Luo, Junhua]Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China
  • [ 12 ] [Chen, Qiushui]Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China
  • [ 13 ] [Sun, Zhihua]Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China
  • [ 14 ] [Rong, Hao]Fujian Sci Technol Innovat Lab Optoelect Informat, Fuzhou 350108, Fujian, Peoples R China
  • [ 15 ] [Yao, Jia-Yu]Fujian Sci Technol Innovat Lab Optoelect Informat, Fuzhou 350108, Fujian, Peoples R China
  • [ 16 ] [Fan, Qingshun]Fujian Sci Technol Innovat Lab Optoelect Informat, Fuzhou 350108, Fujian, Peoples R China
  • [ 17 ] [Zhang, Haoyu]Fujian Sci Technol Innovat Lab Optoelect Informat, Fuzhou 350108, Fujian, Peoples R China
  • [ 18 ] [Xu, Haojie]Fujian Sci Technol Innovat Lab Optoelect Informat, Fuzhou 350108, Fujian, Peoples R China
  • [ 19 ] [Luo, Junhua]Fujian Sci Technol Innovat Lab Optoelect Informat, Fuzhou 350108, Fujian, Peoples R China
  • [ 20 ] [Sun, Zhihua]Fujian Sci Technol Innovat Lab Optoelect Informat, Fuzhou 350108, Fujian, Peoples R China
  • [ 21 ] [Rong, Hao]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Fujian, Peoples R China
  • [ 22 ] [Yao, Jia-Yu]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Fujian, Peoples R China

Reprint 's Address:

  • 孙志华

    [Sun, Zhihua]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Funct Crystals & Devices, Fuzhou 350002, Fujian, Peoples R China;;[Sun, Zhihua]Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China;;[Sun, Zhihua]Fujian Sci Technol Innovat Lab Optoelect Informat, Fuzhou 350108, Fujian, Peoples R China

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Source :

ACS APPLIED MATERIALS & INTERFACES

ISSN: 1944-8244

Year: 2025

Issue: 16

Volume: 17

Page: 24137-24145

8 . 5 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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