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author:

Zhang, Yuhai (Zhang, Yuhai.) [1] | Sun, Ruijia (Sun, Ruijia.) [2] | Qi, Xiangyu (Qi, Xiangyu.) [3] | Fu, Kaifang (Fu, Kaifang.) [4] | Chen, Qiushui (Chen, Qiushui.) [5] | Ding, Yuchong (Ding, Yuchong.) [6] | Xu, Liang-Jin (Xu, Liang-Jin.) [7] | Liu, Lingmei (Liu, Lingmei.) [8] | Han, Yu (Han, Yu.) [9] | Malko, Anton V. (Malko, Anton V..) [10] | Liu, Xiaogang (Liu, Xiaogang.) [11] | Yang, Huanghao (Yang, Huanghao.) [12] (Scholars:杨黄浩) | Bakr, Osman M. (Bakr, Osman M..) [13] | Liu, Hong (Liu, Hong.) [14] | Mohammed, Omar F. (Mohammed, Omar F..) [15]

Indexed by:

Scopus SCIE

Abstract:

Scintillators, which are capable of converting ionizing radiation into visible photons, are an integral part of medical, security, and commercial diagnostic technologies such as X-ray imaging, nuclear cameras, and computed tomography. Conventional scintillator fabrication typically involves high-temperature sintering, generating agglomerated powders or large bulk crystals, which pose major challenges for device integration and processability. On the other hand, colloidal quantum dot scintillators cannot be cast into compact solid films with the necessary thickness required for most X-ray applications. Here, we report the room-temperature synthesis of a colloidal scintillator comprising CsPbBr3 nanosheets of large concentration (up to 150 mg/mL). The CsPbBr3 colloid exhibits a light yield (similar to 21000 photons/MeV) higher than that of the commercially available Ce:LuAG single-crystal scintillator (similar to 18000 photons/MeV). Scintillators based on these nanosheets display both strong radioluminescence (RL) and long-term stability under X-ray illumination. Importantly, the colloidal scintillator can be readily cast into a uniform crack-free large area film (8.5 x 8.5 cm(2) in area) with the requisite thickness for high-resolution X-ray imaging applications. We showcase prototype applications of these high-quality scintillating films as X-ray imaging screens for a cellphone panel and a standard central processing unit chip. Our radiography prototype combines large-area processability with high resolution and a strong penetration ability to sheath materials, such as resin and silicon. We reveal an energy transfer process inside those stacked nanosheet solids that is responsible for their superb scintillation performance. Our findings demonstrate a large-area solution-processed scintillator of stable and efficient RL as a promising approach for low-cost radiography and X-ray imaging applications.

Keyword:

colloidal scintillator energy transfer nanosheets perovskite self-assembly X-ray imaging

Community:

  • [ 1 ] [Zhang, Yuhai]Univ Jinan, Inst Adv Interdisciplinary Res iAIR, Jinan 250022, Shandong, Peoples R China
  • [ 2 ] [Sun, Ruijia]Univ Jinan, Inst Adv Interdisciplinary Res iAIR, Jinan 250022, Shandong, Peoples R China
  • [ 3 ] [Fu, Kaifang]Univ Jinan, Inst Adv Interdisciplinary Res iAIR, Jinan 250022, Shandong, Peoples R China
  • [ 4 ] [Liu, Hong]Univ Jinan, Inst Adv Interdisciplinary Res iAIR, Jinan 250022, Shandong, Peoples R China
  • [ 5 ] [Zhang, Yuhai]King Abdullah Univ Sci & Technol, Div Phys Sci & Engn, Thuwal 239556900, Saudi Arabia
  • [ 6 ] [Xu, Liang-Jin]King Abdullah Univ Sci & Technol, Div Phys Sci & Engn, Thuwal 239556900, Saudi Arabia
  • [ 7 ] [Bakr, Osman M.]King Abdullah Univ Sci & Technol, Div Phys Sci & Engn, Thuwal 239556900, Saudi Arabia
  • [ 8 ] [Mohammed, Omar F.]King Abdullah Univ Sci & Technol, Div Phys Sci & Engn, Thuwal 239556900, Saudi Arabia
  • [ 9 ] [Qi, Xiangyu]Fuzhou Univ, Coll Chem, MOE Key Lab Analyt Sci Food Safety & Biol, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Fujian, Peoples R China
  • [ 10 ] [Yang, Huanghao]Fuzhou Univ, Coll Chem, MOE Key Lab Analyt Sci Food Safety & Biol, State Key Lab Photocatalysis Energy & Environm, Fuzhou 350002, Fujian, Peoples R China
  • [ 11 ] [Chen, Qiushui]Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore
  • [ 12 ] [Liu, Xiaogang]Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore
  • [ 13 ] [Ding, Yuchong]Corp 26 Res Inst, China Elect Technol Grp, Res & Dev Ctr Mat & Equipment, Chongqing 400060, Peoples R China
  • [ 14 ] [Liu, Lingmei]King Abdullah Univ Sci & Technol KAUST, Phys Sci & Engn Div, Adv Membranes & Porous Mat Ctr, Thuwal 239556900, Saudi Arabia
  • [ 15 ] [Han, Yu]King Abdullah Univ Sci & Technol KAUST, Phys Sci & Engn Div, Adv Membranes & Porous Mat Ctr, Thuwal 239556900, Saudi Arabia
  • [ 16 ] [Liu, Lingmei]King Abdullah Univ Sci & Technol KAUST, Phys Sci & Engn Div, Adv Membranes & Porous Mat Ctr, Thuwal 239556900, Saudi Arabia
  • [ 17 ] [Han, Yu]King Abdullah Univ Sci & Technol KAUST, Phys Sci & Engn Div, Adv Membranes & Porous Mat Ctr, Thuwal 239556900, Saudi Arabia
  • [ 18 ] [Malko, Anton V.]Univ Texas Dallas, Dept Phys, Richardson, TX 75080 USA

Reprint 's Address:

  • [Zhang, Yuhai]Univ Jinan, Inst Adv Interdisciplinary Res iAIR, Jinan 250022, Shandong, Peoples R China;;[Liu, Hong]Univ Jinan, Inst Adv Interdisciplinary Res iAIR, Jinan 250022, Shandong, Peoples R China;;[Zhang, Yuhai]King Abdullah Univ Sci & Technol, Div Phys Sci & Engn, Thuwal 239556900, Saudi Arabia;;[Mohammed, Omar F.]King Abdullah Univ Sci & Technol, Div Phys Sci & Engn, Thuwal 239556900, Saudi Arabia

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Source :

ACS NANO

ISSN: 1936-0851

Year: 2019

Issue: 2

Volume: 13

Page: 2520-2525

1 4 . 5 8 8

JCR@2019

1 5 . 8 0 0

JCR@2023

ESI Discipline: MATERIALS SCIENCE;

ESI HC Threshold:236

JCR Journal Grade:1

CAS Journal Grade:1

Cited Count:

WoS CC Cited Count: 373

SCOPUS Cited Count: 393

ESI Highly Cited Papers on the List: 30 Unfold All

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WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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