Polyferrocene　macrocycles　hold　immense　potential　in　the　fields　of　molecular　electronics　and　electrochemistry,primarily　due　to　their　multiple　metal　centers.However,developing　highly　efficient　synthetic　strategies　for　constructing　these　rings　remains　a　significant　challenge.In　this　study,we　successfully　synthesized　tri-ferrocenyl　macrocycles　using　Pt-mediated　coupling　strategy　and　determined　their　configuration　using　single-crystal　X-ray　diffraction　analysis,revealing　a　structure　reminiscent　of　the　Penrose　Stair.We　comprehensively　investigated　the　macrocycle＇s　structure,photophysical　properties,and　employed　density　functional　theory(DFT)calculations　to　gain　further　insights.Notably,this　macrocycle　exhibits　several　advantageous　features,including　a　flexible　structure,good　solubility,and　a　highly　efficient　synthetic　pathway.