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author:

Wu, Weiqing (Wu, Weiqing.) [1] | Xu, Yurong (Xu, Yurong.) [2] | Lin, Xinyi (Lin, Xinyi.) [3] | Huang, Fazheng (Huang, Fazheng.) [4] | Feng, Ya-Nan (Feng, Ya-Nan.) [5] | Zhang, Lizhen (Zhang, Lizhen.) [6] | Yu, Yan (Yu, Yan.) [7] | Li, Lingyun (Li, Lingyun.) [8]

Indexed by:

SCIE

Abstract:

Fluorescence intensity ratio (FIR)-based optical thermometry, recognized for high reliability and rapid response, has emerged as a promising non-contact temperature sensing technology. This study focuses on enhancing the performance of Er3+/Yb3+ co-doped scheelite-type single crystals (NaY(WO4)2 and NaGd(WO4)2) for wide-range optical temperature sensing. By employing a spontaneous nucleation method, we synthesized single crystals with optimized doping concentrations (1 % Er3+/60 % Yb3+ for NYW and 3 % Er3+/70 % Yb3+ for NGW), achieving intense green upconversion (UC) emissions at 530 nm (2H11/2 -> 4I15/2) and 552 nm (4S3/2 -> 4I15/2). The single crystals exhibited high Yb3+-> Er3+ energy transfer efficiencies of 11.02 % (NYW: 1 % Er3+, 60 % Yb3+) and 20.65 % (NGW: 3 % Er3+, 70 % Yb3+), enabling robust UC luminescence even under harsh conditions (pH = 1/ 13, 72 h) and thermal shocks (800 degrees C, 8 cycles). Temperature-dependent FIR analysis of thermally coupled energy levels (2H11/2 and 4S3/2) revealed linear ln(FIR) vs. 1/T relationships, with maximum relative sensitivities of 1.18 % K-1 (NYW) and 1.12 % K-1 (NGW) in 298-578 K. A prototype sensor utilizing NGW: 3 %Er3+, 70 % Yb3+ single crystal demonstrated practical feasibility across 80-780 K, eliminating fiber-optic requirements due to high UC efficiency. These results highlight scheelite-type single crystals as superior candidates for precision optical thermometry in extreme environments.

Keyword:

Fluorescence intensity ratio Optical thermometry Scheelite-type single crystals Temperature sensors Upconversion emission

Community:

  • [ 1 ] [Wu, Weiqing]Fuzhou Univ, Coll Mat Sci & Engn, Key Lab Adv Mat Technol, Int HongKong Macao & Taiwan Joint Lab Adv Mat Tech, Fuzhou 350108, Peoples R China
  • [ 2 ] [Xu, Yurong]Fuzhou Univ, Coll Mat Sci & Engn, Key Lab Adv Mat Technol, Int HongKong Macao & Taiwan Joint Lab Adv Mat Tech, Fuzhou 350108, Peoples R China
  • [ 3 ] [Lin, Xinyi]Fuzhou Univ, Coll Mat Sci & Engn, Key Lab Adv Mat Technol, Int HongKong Macao & Taiwan Joint Lab Adv Mat Tech, Fuzhou 350108, Peoples R China
  • [ 4 ] [Huang, Fazheng]Fuzhou Univ, Coll Mat Sci & Engn, Key Lab Adv Mat Technol, Int HongKong Macao & Taiwan Joint Lab Adv Mat Tech, Fuzhou 350108, Peoples R China
  • [ 5 ] [Feng, Ya-Nan]Fuzhou Univ, Coll Mat Sci & Engn, Key Lab Adv Mat Technol, Int HongKong Macao & Taiwan Joint Lab Adv Mat Tech, Fuzhou 350108, Peoples R China
  • [ 6 ] [Yu, Yan]Fuzhou Univ, Coll Mat Sci & Engn, Key Lab Adv Mat Technol, Int HongKong Macao & Taiwan Joint Lab Adv Mat Tech, Fuzhou 350108, Peoples R China
  • [ 7 ] [Li, Lingyun]Fuzhou Univ, Coll Mat Sci & Engn, Key Lab Adv Mat Technol, Int HongKong Macao & Taiwan Joint Lab Adv Mat Tech, Fuzhou 350108, Peoples R China
  • [ 8 ] [Zhang, Lizhen]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fuzhou 350002, Peoples R China

Reprint 's Address:

  • [Li, Lingyun]Fuzhou Univ, Coll Mat Sci & Engn, Key Lab Adv Mat Technol, Int HongKong Macao & Taiwan Joint Lab Adv Mat Tech, Fuzhou 350108, Peoples R China;;[Zhang, Lizhen]Chinese Acad Sci, Fujian Inst Res Struct Matter, Fuzhou 350002, Peoples R China

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Source :

JOURNAL OF LUMINESCENCE

ISSN: 0022-2313

Year: 2025

Volume: 283

3 . 3 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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