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Abstract:
Lithium/fluorinated carbon (Li/CFx) battery possesses ultra-high energy density, yet the poor conductivity of CFx pose certain limitations on its electrochemical performance. In this work, a CF1.05-SeS2 composite material with both high energy density and power density is prepared. The abundant pore structure of CF1.05 provides ample space for the loading of SeS2 and numerous reaction sites for electrochemical reactions. During 70 % of the discharge depth of CFx, SeS2 can participate the discharge reaction, further enhancing its discharge performance. The CF1.05-SeS2 exhibits excellent electrochemical performance, with maximum energy density reaching 2534 Wh kg-1 and maximum power density of 57,725 W kg- 1 simultaneously. Density functional theory (DFT) calculations reveal that the introduction of SeS2 can reduce the Lithium-ion diffusion energy barrier and increase the Lithium-ion adsorption energy. This work provides new insights into modifying CFx materials to enhance their energy density and power density.
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JOURNAL OF ENERGY STORAGE
ISSN: 2352-152X
Year: 2025
Volume: 124
8 . 9 0 0
JCR@2023
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 0