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author:

Zou, Yan (Zou, Yan.) [1] | Xia, Qi (Xia, Qi.) [2] | Yan, Ke (Yan, Ke.) [3] | Bao, Liangxue (Bao, Liangxue.) [4] | Meng, Lingyi (Meng, Lingyi.) [5] | Han, Xiang (Han, Xiang.) [6] | Chen, Huixin (Chen, Huixin.) [7] | Yue, Hongjun (Yue, Hongjun.) [8]

Indexed by:

EI SCIE

Abstract:

Lithium/fluorinated carbon (Li/CFx) battery possesses ultra-high energy density, yet the poor conductivity of CFx pose certain limitations on its electrochemical performance. In this work, a CF1.05-SeS2 composite material with both high energy density and power density is prepared. The abundant pore structure of CF1.05 provides ample space for the loading of SeS2 and numerous reaction sites for electrochemical reactions. During 70 % of the discharge depth of CFx, SeS2 can participate the discharge reaction, further enhancing its discharge performance. The CF1.05-SeS2 exhibits excellent electrochemical performance, with maximum energy density reaching 2534 Wh kg-1 and maximum power density of 57,725 W kg- 1 simultaneously. Density functional theory (DFT) calculations reveal that the introduction of SeS2 can reduce the Lithium-ion diffusion energy barrier and increase the Lithium-ion adsorption energy. This work provides new insights into modifying CFx materials to enhance their energy density and power density.

Keyword:

Density functional theory Excellent electrochemical performance Fluorinated carbon Lithium primary batteries Selenium disulfide

Community:

  • [ 1 ] [Zou, Yan]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 2 ] [Xia, Qi]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 3 ] [Yan, Ke]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 4 ] [Bao, Liangxue]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 5 ] [Meng, Lingyi]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 6 ] [Chen, Huixin]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 7 ] [Yue, Hongjun]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China
  • [ 8 ] [Zou, Yan]Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China
  • [ 9 ] [Yan, Ke]Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China
  • [ 10 ] [Han, Xiang]Nanjing Forestry Univ, Coll Mat Sci & Engn, Coinnovat Ctr Efficient Proc & Utilizat Forest Res, Nanjing 210037, Peoples R China
  • [ 11 ] [Zou, Yan]Chinese Acad Sci, Xiamen Inst Rare Earth Mat, Haixi Inst, Xiamen Key Lab Rare Earth Photoelect Funct Mat, Xiamen 361021, Fujian, Peoples R China
  • [ 12 ] [Xia, Qi]Chinese Acad Sci, Xiamen Inst Rare Earth Mat, Haixi Inst, Xiamen Key Lab Rare Earth Photoelect Funct Mat, Xiamen 361021, Fujian, Peoples R China
  • [ 13 ] [Yan, Ke]Chinese Acad Sci, Xiamen Inst Rare Earth Mat, Haixi Inst, Xiamen Key Lab Rare Earth Photoelect Funct Mat, Xiamen 361021, Fujian, Peoples R China
  • [ 14 ] [Bao, Liangxue]Chinese Acad Sci, Xiamen Inst Rare Earth Mat, Haixi Inst, Xiamen Key Lab Rare Earth Photoelect Funct Mat, Xiamen 361021, Fujian, Peoples R China
  • [ 15 ] [Meng, Lingyi]Chinese Acad Sci, Xiamen Inst Rare Earth Mat, Haixi Inst, Xiamen Key Lab Rare Earth Photoelect Funct Mat, Xiamen 361021, Fujian, Peoples R China
  • [ 16 ] [Chen, Huixin]Chinese Acad Sci, Xiamen Inst Rare Earth Mat, Haixi Inst, Xiamen Key Lab Rare Earth Photoelect Funct Mat, Xiamen 361021, Fujian, Peoples R China
  • [ 17 ] [Yue, Hongjun]Chinese Acad Sci, Xiamen Inst Rare Earth Mat, Haixi Inst, Xiamen Key Lab Rare Earth Photoelect Funct Mat, Xiamen 361021, Fujian, Peoples R China
  • [ 18 ] [Zou, Yan]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Fujian, Peoples R China
  • [ 19 ] [Xia, Qi]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Fujian, Peoples R China
  • [ 20 ] [Yan, Ke]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Fujian, Peoples R China
  • [ 21 ] [Bao, Liangxue]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Fujian, Peoples R China
  • [ 22 ] [Meng, Lingyi]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Fujian, Peoples R China
  • [ 23 ] [Chen, Huixin]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Fujian, Peoples R China
  • [ 24 ] [Yue, Hongjun]Univ Chinese Acad Sci, Fujian Coll, Fuzhou 350002, Fujian, Peoples R China

Reprint 's Address:

  • [Chen, Huixin]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China;;[Yue, Hongjun]Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

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Source :

JOURNAL OF ENERGY STORAGE

ISSN: 2352-152X

Year: 2025

Volume: 124

8 . 9 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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