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author:

Luo, Lu (Luo, Lu.) [1] | Li, Wenfeng (Li, Wenfeng.) [2] | Wang, Shanhao (Wang, Shanhao.) [3] | Hu, Ziying (Hu, Ziying.) [4] | Wang, Yiqi (Wang, Yiqi.) [5] | Wen, Jinlong (Wen, Jinlong.) [6] | Chen, Jing (Chen, Jing.) [7] | Lu, Can-Zhong (Lu, Can-Zhong.) [8]

Indexed by:

EI

Abstract:

Organic-inorganic hybrid semiconductors have good prospects in photocatalysis for the enhanced light absorption and photo-generated charges separation. Organic semiconductor tetrathiafulvalene (TTF) shows excellent optical and electrical properties, widely studied in photoelectric materials and devices. Herein, TTF modified ZnS with four different morphologies were obtained, and the effect of morphology for the photocatalytic H2 evolution performance was explored. The photocatalytic performance is superior when 2 wt% TTF is combined with 98 wt% ZnS spheres, exhibiting the best photocatalytic hydrogen production capability, reaching 4221 μmol g−1 h−1.The tight contact and interaction between TTF and ZnS facilitate the transport of photo-generated carriers and minimized the recombination of hole-electron pairs, thereby enhancing the photocatalytic performance. This work demonstrates that the tight interface connection between organic and inorganic components is a key to constructing high performance semiconductor photocatalysts for hydrogen production. © 2025 Hydrogen Energy Publications LLC

Keyword:

Organic-inorganic materials Photocatalytic activity Phototransistors Semiconducting indium phosphide Wide band gap semiconductors

Community:

  • [ 1 ] [Luo, Lu]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou; 350002, China
  • [ 2 ] [Luo, Lu]College of Chemistry and Materials Science, Fujian Normal University, Fujian, Fuzhou; 350007, China
  • [ 3 ] [Luo, Lu]Xiamen Institute of Rare-earth Materials, Haixi Institutes, Chinese Academy of Sciences, Fujian, Xiamen; 361021, China
  • [ 4 ] [Luo, Lu]Fujian College, University of Chinese Academy of Sciences, Fuzhou; 350002, China
  • [ 5 ] [Li, Wenfeng]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou; 350002, China
  • [ 6 ] [Li, Wenfeng]College of Chemistry and Materials Science, Fujian Normal University, Fujian, Fuzhou; 350007, China
  • [ 7 ] [Li, Wenfeng]Xiamen Institute of Rare-earth Materials, Haixi Institutes, Chinese Academy of Sciences, Fujian, Xiamen; 361021, China
  • [ 8 ] [Li, Wenfeng]Fujian College, University of Chinese Academy of Sciences, Fuzhou; 350002, China
  • [ 9 ] [Wang, Shanhao]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou; 350002, China
  • [ 10 ] [Wang, Shanhao]College of Chemistry and Materials Science, Fujian Normal University, Fujian, Fuzhou; 350007, China
  • [ 11 ] [Wang, Shanhao]Xiamen Institute of Rare-earth Materials, Haixi Institutes, Chinese Academy of Sciences, Fujian, Xiamen; 361021, China
  • [ 12 ] [Wang, Shanhao]Fujian College, University of Chinese Academy of Sciences, Fuzhou; 350002, China
  • [ 13 ] [Hu, Ziying]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou; 350002, China
  • [ 14 ] [Hu, Ziying]Xiamen Institute of Rare-earth Materials, Haixi Institutes, Chinese Academy of Sciences, Fujian, Xiamen; 361021, China
  • [ 15 ] [Hu, Ziying]College of Chemistry, Fuzhou University, Fujian, Fuzhou; 350106, China
  • [ 16 ] [Hu, Ziying]Fujian College, University of Chinese Academy of Sciences, Fuzhou; 350002, China
  • [ 17 ] [Wang, Yiqi]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou; 350002, China
  • [ 18 ] [Wang, Yiqi]College of Chemistry and Materials Science, Fujian Normal University, Fujian, Fuzhou; 350007, China
  • [ 19 ] [Wang, Yiqi]Xiamen Institute of Rare-earth Materials, Haixi Institutes, Chinese Academy of Sciences, Fujian, Xiamen; 361021, China
  • [ 20 ] [Wang, Yiqi]Fujian College, University of Chinese Academy of Sciences, Fuzhou; 350002, China
  • [ 21 ] [Wen, Jinlong]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou; 350002, China
  • [ 22 ] [Wen, Jinlong]Xiamen Institute of Rare-earth Materials, Haixi Institutes, Chinese Academy of Sciences, Fujian, Xiamen; 361021, China
  • [ 23 ] [Wen, Jinlong]College of Chemistry, Fuzhou University, Fujian, Fuzhou; 350106, China
  • [ 24 ] [Wen, Jinlong]Fujian College, University of Chinese Academy of Sciences, Fuzhou; 350002, China
  • [ 25 ] [Chen, Jing]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou; 350002, China
  • [ 26 ] [Chen, Jing]Xiamen Institute of Rare-earth Materials, Haixi Institutes, Chinese Academy of Sciences, Fujian, Xiamen; 361021, China
  • [ 27 ] [Chen, Jing]Fujian College, University of Chinese Academy of Sciences, Fuzhou; 350002, China
  • [ 28 ] [Lu, Can-Zhong]State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou; 350002, China
  • [ 29 ] [Lu, Can-Zhong]Xiamen Institute of Rare-earth Materials, Haixi Institutes, Chinese Academy of Sciences, Fujian, Xiamen; 361021, China
  • [ 30 ] [Lu, Can-Zhong]Fujian College, University of Chinese Academy of Sciences, Fuzhou; 350002, China

Reprint 's Address:

  • [chen, jing]xiamen institute of rare-earth materials, haixi institutes, chinese academy of sciences, fujian, xiamen; 361021, china;;[chen, jing]fujian college, university of chinese academy of sciences, fuzhou; 350002, china;;[chen, jing]state key laboratory of structural chemistry, fujian institute of research on the structure of matter, chinese academy of sciences, fujian, fuzhou; 350002, china

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Source :

International Journal of Hydrogen Energy

ISSN: 0360-3199

Year: 2025

Volume: 131

Page: 165-176

8 . 1 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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