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author:

Peng Guo (Peng Guo.) [1] | Shicheng Dong (Shicheng Dong.) [2] | Xiang-Gui Zhang (Xiang-Gui Zhang.) [3] | Bing-Bin Yang (Bing-Bin Yang.) [4] | Jun Zhu (Jun Zhu.) [5] | Ke-Yin Ye (Ke-Yin Ye.) [6]

Abstract:

In most Suzuki-Miyaura carbon-carbon cross-coupling reactions,the borabicyclo[3.3.1]nonane scaffold(9-BBN)only serves as an auxiliary facilitating the transmetalation step and thus is transformed into by-products.There are rare examples where the 9-BBN derivatives serve as the potentially diverse C8 building blocks in cross-coupling reactions.Herein,we report a cobalt-catalyzed migratory carbon-carbon cross-coupling reaction of the in situ formed 9-BBN ate complexes to afford diverse aryl-and alkyl-functionalized cyclooctenes.Preliminary mechanistic studies suggest the oxidation-induced cis-bicyclo[3.3.0]oct-1-ylborane is the key intermediate in this migratory cross-coupling reaction,which pro-motes the development of other diverse migratory cross-coupling of borate complexes.

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  • [ 1 ] [Xiang-Gui Zhang]福州大学
  • [ 2 ] [Jun Zhu]School of Science and Engineering,The Chinese University of Hong Kong,Shenzhen 518172,China;State Key Laboratory of Physical Chemistry of Solid Surfaces and Collaborative Innovation Center of Chemistry for Energy Materials(iChEM),Fujian Provincial Key Laboratory of Theoretical and Computational Chemistry,Department of Chemistry,College of Chemistry and Chemical Engineering,Xiamen University,Xiamen 361005,China
  • [ 3 ] [Bing-Bin Yang]福州大学
  • [ 4 ] [Ke-Yin Ye]福州大学
  • [ 5 ] [Shicheng Dong]State Key Laboratory of Physical Chemistry of Solid Surfaces and Collaborative Innovation Center of Chemistry for Energy Materials(iChEM),Fujian Provincial Key Laboratory of Theoretical and Computational Chemistry,Department of Chemistry,College of Chemistry and Chemical Engineering,Xiamen University,Xiamen 361005,China
  • [ 6 ] [Peng Guo]福州大学

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中国化学快报(英文版)

ISSN: 1001-8417

Year: 2025

Issue: 4

Volume: 36

Page: 139-143

9 . 4 0 0

JCR@2023

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ESI Highly Cited Papers on the List: 0 Unfold All

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30 Days PV: 0

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