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author:

Liu, Yan (Liu, Yan.) [1] | Zhu, Yanjun (Zhu, Yanjun.) [2] | Chen, Jie (Chen, Jie.) [3] | Shi, Yongqian (Shi, Yongqian.) [4] | Zhang, Yijie (Zhang, Yijie.) [5] | Fu, Libi (Fu, Libi.) [6] | Tang, Longcheng (Tang, Longcheng.) [7] | Gao, Jiefeng (Gao, Jiefeng.) [8] | Song, Pingan (Song, Pingan.) [9] | Qiu, Ting (Qiu, Ting.) [10]

Indexed by:

SCIE

Abstract:

In extreme environments, the simultaneous presence of mechanical impact and fire hazards poses significant challenges for single flexible polyurethane foam (FPUF) protective materials. To address these limitations, we developed an innovative multilayer coating structure for FPUF using a simple dip-drying method. This structure comprises a polydopamine (PDA) base layer, an intermediate layer containing ammonium polyphosphate (APP), carboxymethyl chitosan (CMC), and halloysite nanotubes (HNT), and a top layer of polydimethylsiloxane (PDMS). The multilayer coating significantly enhanced the cushioning and flame-retardant properties of FPUF. At a coating loading of 35 wt.%, the FPUF@PDA/A-C-H/PDMS exhibited a compressive strength 3.52 times higher than pure FPUF, with only a 10.2 % decrease after 100 compression cycles. The composite effectively dissipated 95.7 % of an impact energy of 1.22 J, achieving a 97.1 % impact force dissipation rate and significantly extending cushioning duration. The FPUF@PDA/A-C-H/PDMS demonstrated self-extinguishing properties after 10 s of exposure to a butane flame, maintaining structural integrity. Moreover, its peak heat release rate was reduced by 68.8 %. The multilayer coating also improved hydrophobicity and thermal insulation. This multifunctional foam composite shows great potential for enhancing the performances of FPUF in hazardous environments, offering robust protection in extreme conditions.

Keyword:

Durability Flame retardancy Impact resistance Multifunctional coating Thermal insulation

Community:

  • [ 1 ] [Liu, Yan]Fuzhou Univ, Coll Environm & Safety Engn, Fuzhou 350108, Peoples R China
  • [ 2 ] [Zhu, Yanjun]Fuzhou Univ, Coll Environm & Safety Engn, Fuzhou 350108, Peoples R China
  • [ 3 ] [Shi, Yongqian]Fuzhou Univ, Coll Environm & Safety Engn, Fuzhou 350108, Peoples R China
  • [ 4 ] [Zhang, Yijie]Fuzhou Univ, Coll Environm & Safety Engn, Fuzhou 350108, Peoples R China
  • [ 5 ] [Chen, Jie]Fujian Prov Univ, Fuzhou Univ, Coll Chem Engn, Engn Res Ctr React Distillat, Fuzhou 350108, Peoples R China
  • [ 6 ] [Qiu, Ting]Fujian Prov Univ, Fuzhou Univ, Coll Chem Engn, Engn Res Ctr React Distillat, Fuzhou 350108, Peoples R China
  • [ 7 ] [Fu, Libi]Fuzhou Univ, Coll Civil Engn, Fuzhou 350108, Peoples R China
  • [ 8 ] [Tang, Longcheng]Hangzhou Normal Univ, Minist Educ, Coll Mat Chem & Chem Engn, Key Lab Organosilicon Chem & Mat Technol, Hangzhou 311121, Peoples R China
  • [ 9 ] [Gao, Jiefeng]Yangzhou Univ, Sch Chem & Chem Engn, Yangzhou 225002, Peoples R China
  • [ 10 ] [Song, Pingan]Univ Southern Queensland, Sch Agr & Environm Sci, Springffeld, Qld 4300, Australia

Reprint 's Address:

  • [Shi, Yongqian]Fuzhou Univ, Coll Environm & Safety Engn, Fuzhou 350108, Peoples R China;;[Qiu, Ting]Fujian Prov Univ, Fuzhou Univ, Coll Chem Engn, Engn Res Ctr React Distillat, Fuzhou 350108, Peoples R China;;[Fu, Libi]Fuzhou Univ, Coll Civil Engn, Fuzhou 350108, Peoples R China

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Source :

POLYMER DEGRADATION AND STABILITY

ISSN: 0141-3910

Year: 2025

Volume: 239

6 . 3 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 1

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