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author:

Li, Hao (Li, Hao.) [1] | Cui, Lianmeng (Cui, Lianmeng.) [2] | Wu, Fanglin (Wu, Fanglin.) [3] | Wang, Jian (Wang, Jian.) [4] | Cheng, Yapeng (Cheng, Yapeng.) [5] | Li, Canhuang (Li, Canhuang.) [6] | Song, Jiangping (Song, Jiangping.) [7] | Li, Yafeng (Li, Yafeng.) [8] | Liu, Dan (Liu, Dan.) [9] | Cabot, Andreu (Cabot, Andreu.) [10] | Zhang, Chaoqi (Zhang, Chaoqi.) [11] | Tang, Haolin (Tang, Haolin.) [12]

Indexed by:

Scopus SCIE

Abstract:

Inadequate ionic transport across the electrode/electrolyte interface hampers the lithium-sulfur reaction kinetics, thereby limiting the electrochemical performance of all-solid-state lithium-sulfur batteries (ASSLSBs). Herein, a kinetically-enhanced gradient modulator layer (KEGML) is proposed and fabricated via potential modulation. In situ/ex situ analyses reveal the optimal modulated potential difference driving the chemical reaction between Li ions and the P2S5 pre-interphase product for stabilized KEGML and maintained full-sulfur conversion. Cryo-focused ion beam-scanning electron microscopy characterization and ab-initio molecular dynamics confirm the interfacial reinforcement by gradient uniformization of ion transport and enhanced interface stability by efficiently avoiding the side effects between sulfur/sulfides solid electrolyte/carbon, respectively. As a result, an eightfold increase in ionic transport capability is achieved with KEGML at the end of the 200 cycles. Impressively, KEGML-based ASSLSBs not only accelerate the redox conversions but also display an exceptional cycling stability of a specific capacity of 1578.9 mAh g(-1) for approximate to 1.5 years with a 99.9% capacity retention and a high areal capacity of 13 mAh cm(-2) over 200 cycles, which is among the record-level. Even in the ambient environment from 60 degrees C to as low as -30 degrees C, it exhibits excellent adaptivity attributed to the fast kinetics, shedding light on future practical applications.

Keyword:

all-solid-state lithium-sulfur battery electrode/electrolyte interface solid electrolyte ultralong life wide-temperature range

Community:

  • [ 1 ] [Li, Hao]Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Hubei, Peoples R China
  • [ 2 ] [Cui, Lianmeng]Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Hubei, Peoples R China
  • [ 3 ] [Wu, Fanglin]Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Hubei, Peoples R China
  • [ 4 ] [Li, Yafeng]Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Hubei, Peoples R China
  • [ 5 ] [Tang, Haolin]Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Hubei, Peoples R China
  • [ 6 ] [Li, Hao]Wuhan Univ Technol, Hubei Key Lab Fuel Cells, Wuhan 430070, Hubei, Peoples R China
  • [ 7 ] [Wu, Fanglin]Wuhan Univ Technol, Hubei Key Lab Fuel Cells, Wuhan 430070, Hubei, Peoples R China
  • [ 8 ] [Li, Yafeng]Wuhan Univ Technol, Hubei Key Lab Fuel Cells, Wuhan 430070, Hubei, Peoples R China
  • [ 9 ] [Liu, Dan]Wuhan Univ Technol, Hubei Key Lab Fuel Cells, Wuhan 430070, Hubei, Peoples R China
  • [ 10 ] [Tang, Haolin]Wuhan Univ Technol, Hubei Key Lab Fuel Cells, Wuhan 430070, Hubei, Peoples R China
  • [ 11 ] [Wang, Jian]Karlsruhe Inst Technol KIT, POB 3640, D-7621 Karlsruhe, Germany
  • [ 12 ] [Wang, Jian]Helmholtz Inst Ulm HIU, Helmholtzstr 11, D-89081 Ulm, Germany
  • [ 13 ] [Cheng, Yapeng]Catalonia Inst Energy Res IREC St Adria Besos, Barcelona 08930, Spain
  • [ 14 ] [Li, Canhuang]Catalonia Inst Energy Res IREC St Adria Besos, Barcelona 08930, Spain
  • [ 15 ] [Cabot, Andreu]Catalonia Inst Energy Res IREC St Adria Besos, Barcelona 08930, Spain
  • [ 16 ] [Song, Jiangping]Adv Energy Sci & Technol Guangdong Lab, Foshan Xianhu Lab, Foshan 528200, Peoples R China
  • [ 17 ] [Tang, Haolin]Adv Energy Sci & Technol Guangdong Lab, Foshan Xianhu Lab, Foshan 528200, Peoples R China
  • [ 18 ] [Cabot, Andreu]ICREA Pg Lluis Co, Barcelona 08010, Spain
  • [ 19 ] [Zhang, Chaoqi]Fuzhou Univ, Coll Mat Sci & Engn, Fuzhou 350108, Fujian, Peoples R China

Reprint 's Address:

  • [Tang, Haolin]Wuhan Univ Technol, State Key Lab Adv Technol Mat Synth & Proc, Wuhan 430070, Hubei, Peoples R China;;[Liu, Dan]Wuhan Univ Technol, Hubei Key Lab Fuel Cells, Wuhan 430070, Hubei, Peoples R China;;[Tang, Haolin]Wuhan Univ Technol, Hubei Key Lab Fuel Cells, Wuhan 430070, Hubei, Peoples R China;;[Cabot, Andreu]Catalonia Inst Energy Res IREC St Adria Besos, Barcelona 08930, Spain;;[Tang, Haolin]Adv Energy Sci & Technol Guangdong Lab, Foshan Xianhu Lab, Foshan 528200, Peoples R China;;[Cabot, Andreu]ICREA Pg Lluis Co, Barcelona 08010, Spain

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Source :

ADVANCED ENERGY MATERIALS

ISSN: 1614-6832

Year: 2025

2 4 . 4 0 0

JCR@2023

Cited Count:

WoS CC Cited Count:

SCOPUS Cited Count:

ESI Highly Cited Papers on the List: 0 Unfold All

WanFang Cited Count:

Chinese Cited Count:

30 Days PV: 0

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