The　construction　of　covalent　adaptable　networks　(CANs)　without　requiring　post-modification,　complex　monomer　synthesis　routes,　or　expensive　materials　is　highly　desirable　for　advancing　the　practical　application　of　dynamic　covalent　chemistry.　In　this　study,　the　commercially　available　acrylate　monomer,　diacetone　acrylamide　(DAAM)　was　first　polymerized　using　a　conventional,　free　radical　polymerization　method.　Subsequently,　the　resulting　polymer　was　cross-linked　with　amine-based　agents　under　hot-processing　conditions　to　form　aliphatic　imine-linked　CANs.　The　obtained　materials　exhibited　glass　transition　temperatures　(Tg)　ranging　from　95　to　107 °C,　along　with　good　thermal　stability,　mechanical,　and　thermomechanical　properties.　All　samples　demonstrated　mechanical　recyclability　with　post-recycled　specimens　retaining　approximately　80%　of　their　original　tensile　strength　and　Young＇s　modulus,　indicating　a　slight　deterioration.　Gel　content　analysis　and　structural　characterization　of　both　pristine　and　recycled　samples　indicate　that　the　observed　reduction　in　mechanical　properties　and　Tg　(by　70 °C)　originated　from　a　decrease　a　cross-linking　density　and　partial　cleavage　of　aliphatic　ketone　moieties.　Furthermore,　the　aliphatic　imine　structure　endowed　all　samples　with　acid-triggered　degradability.　This　facile　strategy　for　fabricating　acrylate-based　imine　CANs　establishes　a　versatile　framework　for　developing　reprocessable　and　hydrolyzable　polymeric　materials.　©　2025　Wiley-VCH　GmbH.