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When the leaching method is applied to fine-grained non-ferrous metal ores, challenges such as slow settling rates and inefficient solid–liquid separation often arise. The precipitation of ultrafine silica particles in the acid leaching slurry and their subsequent separation from the leachate play a critical role in determining the overall efficiency of the hydrometallurgical process. To address these issues, this study employs carrier flocculation technology to treat fine quartz particles under acidic conditions. Experimental results indicate that under optimal conditions—specifically, a carrier dosage of 70%, particle size of 160–200 mesh, and flocculant dosage of 150 g/t polyethylene oxide (PEO)—the flocculation and sedimentation of fine quartz particles are significantly enhanced, primarily due to an increased settling rate. The introduction of electrolyte ions improved the clarity of the supernatant, with divalent ions exhibiting the most pronounced effect. Zeta potential measurements revealed that the absolute values under optimal conditions were closest to the isoelectric point, indicating reduced electrostatic repulsion. Focused beam reflectance measurement (FBRM) analysis further demonstrated that the carrier flocculation mechanism improved both the settling rate and supernatant clarity by altering the fine particle composition of the slurry. Calculations based on classical DLVO theory showed that PEO adsorption reduced the potential energy barrier between quartz particles, facilitating their aggregation through interparticle collisions and thereby promoting floc growth. © 2025 Taylor & Francis Group, LLC.
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Particulate Science and Technology
ISSN: 0272-6351
Year: 2025
2 . 3 0 0
JCR@2023
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ESI Highly Cited Papers on the List: 0 Unfold All
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30 Days PV: 1
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